CAS Number: 5593-70-4
Product Catalog

93-2204

Titanium › Titanium(IV) n-butoxide, 98+%

Stability: moisture sensitive

Physical Characteristics: melting point -55°C, boiling point 312°C (206°C/10mm), flash point 170°F, density 0.994 (25°C)

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SECTION 1: Product Identification
Chemical Name:	Titanium (IV) n-butoxide, 98+%
Product Number:	93-2204
CAS Registry Number:	5593-70-4
Formula:	Ti(OC4H9)4
EINECS Number:	227-006-8
Chemical Family:	metal alkoxide
Synonym:	1-Butanol, titanium(4+)salt, Butyl orthotitanate, Titanium tetrabutoxide

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	5593-70-4	100	no data	no data

SECTION 3: Hazards Identification
Emergency Overview:	The liquid irritates the skin, eyes and respiratory system. Moisture will produce titanium oxide powder and n-butanol vapor which may cause severe eye irritation and drowsiness. May be harmful if swallowed.
Primary Routes of Exposure:	Inhalation, ingestion, contact with skin and eyes.
Eye Contact:	If liquid contacts the eye, irritating titanium oxide may form n-butanol vapor from hydrolyzed product may cause eye irritation.
Skin Contact:	Dehydrating agent. Liquid causes mild irritation of the skin.
Inhalation:	Irritating to the respiratory tract. May cause headache, dizziness and drowsiness.
Ingestion:	Ingestion may cause gastrointestinal distress, nausea, vomiting and headache.
Acute Health Effects:	No data is available for this product. Titanium oxide hydrolysis product exhibits low toxicity. n-butanol causes severe eye irritation, drowsiness, and gastrointestinal distress.
Chronic Health Effects:	No data is available for this product. In animal studies, n-butanol in high doses has acted as a reproductive effector.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	170°F
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	carbon dioxide, dry powder or foam.
Special Fire Fighting Procedures:	If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure self-contained breathing apparatus.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic organic fumes and titanium dust.
Unusual Fire or Explosion Hazards:	Combustible liquid. No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be absorbed into vermiculite or other suitable adsorbent. Sweep up the material and dispose of properly.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a tightly sealed container in a dry place. If container is left open, product may absorb moisture from the atmosphere and release n-butanol vapor.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear protective clothing and gloves.
Ventilation:	Material may form a vapor upon exposure to air. If possible, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	colorless liquid
Molecular Weight:	340.35
Melting Point:	-55°C
Boiling Point:	312°C (206°C/10mm)
Vapor Pressure:	no data
Specific Gravity:	0.994 (25�)
Odor:	sweet odor
Solubility in Water:	reacts with water

SECTION 10: Stability and Reactivity
Stability:	moisture sensitive liquid, (store cold)
Hazardous Polymerization:	No hazardous polymerization.
Conditions to Avoid:	contact with moisture
Incompatibility:	water, mineral acids, halogens and strong oxidizing agents.
Decomposition Products:	carbon monoxide, carbon dioxide, titanium oxide and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	Oral (rat); LD50: 3122 mg/kg. Intravenous (mouse); 180 mg/kg.
Carcinogenic Effects:	no data
Mutagenic Effects:	no data
Tetratogenic Effects:	no data

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Non-hazardous
Hazard Class (CFR):	NA
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	NA
UN ID Number (CFR):	NA
Shipping Name (IATA):	Non-hazardous
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	NA

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	2/09/2004
Revision Date:	9/07/2011