CAS Number: 17927-72-9
Product Catalog

93-2203

Titanium › Titanium (di-i-propoxide)bis(acetylacetonate) (75% in isopropanol)

Stability: moisture sensitive

Safety: Hazardous

Physical Characteristics: flash point 72°F (isopropanol), density 0.995

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SECTION 1: Product Identification
Chemical Name:	Titanium (di-i-propoxide)bis(acetylacetonate) (75% in isopropanol)
Product Number:	93-2203
CAS Registry Number:	17927-72-9
Formula:	Ti(OC3H7)2(CH3COCHCOCH3)2
EINECS Number:	241-866-1
Chemical Family:	metal beta-diketonate complexes
Synonym:	Titanium bis(acetylacetonate)(di-i-propoxide)(75% in isopropanol)

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	17927-72-9	75	no data	no data
isopropanol	67-63-8	25	400ppm	980mg/m3

SECTION 3: Hazards Identification
Emergency Overview:	Harmful if swallowed. Irritating to eyes and skin. Possible risk of impaired fertility. In animal studies isopropanol has given mutagenic, tumorigenic, and reproductive effect responses.
Primary Routes of Exposure:	Inhalation, ingestion, skin and eyes.
Eye Contact:	Causes moderate to severe irritation of the eyes.
Skin Contact:	Causes moderate irritation of the skin.
Inhalation:	Vapor may be irritating to the nose, mucous membranes and respiratory tract and cause headache, dizziness, and drowsiness.
Ingestion:	Harmful if swallowed. Ingestion may cause gastrointestinal distress, nausea vomiting and headache, and coma.
Acute Health Effects:	No data of first ingredient. Isopropanol is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time. Large exposures can cause coma.
Chronic Health Effects:	Possible risk of impaired fertility. In animal studies isopropanol has acted as a mutagen, tumorigen and reproductive effector. Prolonged exposure can damage nerves, kidneys, and the cardiovascular system.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
Flash Point:	72°F (isopropanol)
Autoignition Temperature:	750 °F(isopropanol
Explosion Limits:	2.5-12%(isopropanol)
Extinguishing Medium:	carbon dioxide, dry powder or foam
Special Fire Fighting Procedures:	If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards:	Highly flammable material. Formation of explosive air/vapor mixtures is possible.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Eliminate all ignition sources. Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up.

SECTION 7: Handling and Storage
Handling and Storage:	Store in a tightly sealed container in a dry place. If container is left open, salt may adsorb moisture from the atmosphere and release additional isopropanol vapor.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:	Work with this product in a well-ventilated area, preferably a fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	orange liq.
Molecular Weight:	364.27
Melting Point:	no data
Boiling Point:	no data
Vapor Pressure:	no data
Specific Gravity:	0.995
Odor:	alcohol odor
Solubility in Water:	reacts with water

SECTION 10: Stability and Reactivity
Stability:	moisture sensitive
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	Contact with moisture
Incompatibility:	water, mineral acids, alkali metals, oxidizing agents, and halogens
Decomposition Products:	Carbon dioxide, carbon monoxide, organic vapors, and titanium oxides and carbonates.

SECTION 11: Toxicological Information
RTECS Data:	No specific information available on this product. Isopropanol: skin (rabbit) Draize: mild; eye (rabbit) Draize: severe; oral (human) tdlo: 223 mg/Kg; oral (human) ldlo: 5272 mg/kg; oral (human) ldlo: 3570 mg/kg; oral (rat) ld50: 5045 mg/kg; inhalation (rat) lc50:16000 ppm/8h.
Carcinogenic Effects:	Isopropanol: Tumorigen
Mutagenic Effects:	Isopropanol: Mutagen
Tetratogenic Effects:	Isopropanol: Reproductive effector

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Flammable Liquids, N.O.S.
Hazard Class (CFR):	3
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	II
UN ID Number (CFR):	UN# 1993
Shipping Name (IATA):	Flammable Liquid, N.O.S.
Hazard Class (IATA):	3
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	II
UN ID Number (IATA):	UN# 1993

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed.
Second Ingredient:	isopropanol (mfg-strong acid process): listed
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	5/07/2001
Revision Date:	12/16/2011