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CAS Number: 2171-99-5
Product Catalog

72-5950
Hafnium Hafnium(IV) i-propoxide monoisopropylate, 99%
CAS Number: 2171-99-5
MDL Number: MFCD00070460
Molecular Formula: C12H28HfO4
Molecular Weight: 414.84 (474.94)
Chemical Formula: Hf(OC3H7)4·C3H7OH
Color and Form: white xtl.
Note:  

Stability: moisture sensitive

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SECTION 1: Product Identification
Chemical Name: Hafnium (IV) i-propoxide monoisopropylate, 99%
Product Number: 72-5950
CAS Registry Number: 2171-99-5
Formula: Hf(OC3H7)4.C3H7OH
EINECS Number:
Chemical Family: metal alkoxide
Synonym: ytterbium isopropanolate, isopropanol, ytterbium salt.
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 2171-99-5 100 0.5mg/m3 (as Hf) 0.5mg/m3 (as Hf)
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Inhalation, ingestion, contact with skin and eyes.
Eye Contact: The dust and the isopropanol released on hydrolysis will cause moderate to severe irritation of the eyes.
Skin Contact: Dehydrating agent. Dust will cause mild irritation of the skin.
Inhalation: Dust will cause moderate irritation to the upper respiratory tract. isopropanol vapor may cause dizziness and drowsiness
Ingestion: Ingestion may cause moderate irritation of the gastrointestinal tract, nausea, vomiting, headache, and coma.
Acute Health Effects: The product is alkaline and a moderate irritant. isopropanol is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time.
Chronic Health Effects: No data is available for this product. Isopropanol is a possible mutagen, tumorigen and reproductive effector. Prolonged exposure may damage nerves, kidneys, and the cardiovascular system.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container in a dry place. If container is left open, product may adsorb moisture and carbon dioxide from the atmosphere and release isopropanol vapor.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 414.84 (474.94)
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: alcohol-like odor
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: air and moisture sensitive solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: oxidizing agents
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 2/26/2001
Revision Date: 12/13/2011

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