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CAS Number: 14717-56-7
Product Catalog
40-4016
Zirconium › Zirconium(IV) i-propoxide (isopropanol adduct) (99.9%-Zr)| CAS Number: | 14717-56-7 |
| MDL Number: | MFCD00078045 |
| Molecular Formula: | C12H28O4Zr |
| Molecular Weight: | 327.56 (387.67) |
| Chemical Formula: | Zr(OC3H7)4·C3H7OH |
| Color and Form: | white xtl. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: boiling point dec.
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Zirconium (IV) i-propoxide (isopropanol adduct) (99.9%-Zr) |
| Product Number: | 40-4016 |
| CAS Registry Number: | 14717-56-7 |
| Formula: | Zr(OC3H7)4.C3H7OH |
| EINECS Number: | |
| Chemical Family: | metal alkoxide |
| Synonym: | zirconium isopropanolate, isopropanol adduct. |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 14717-56-7 | 85 | 5mg/m3 (as Zr) | 5mg/m3 (as Zr) |
| isopropanol | 67-63-0 | 15 | 200ppm | 980mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Irritating to eyes, skin and respiratory tract. Exposure may cause drowsiness and impairment of coordination and reaction time. |
| Primary Routes of Exposure: | Inhalation, ingestion, contact with skin and eyes. |
| Eye Contact: | Causes moderate to severe irritation of the eyes. |
| Skin Contact: | Causes moderate irritation of the skin. |
| Inhalation: | Isopropanol vapor is irritating to the nose and respiratory tract. May cause headache, dizziness, and drowsiness. |
| Ingestion: | Ingestion may cause gastrointestinal distress, nausea vomiting and headache, and coma. |
| Acute Health Effects: | Irritating to skin, eyes and respiratory tract. Exposure may cause impairment of coordination and reaction time. Large exposures can cause coma. |
| Chronic Health Effects: | In animal studies isopropanol has acted as a mutagen, tumorigen and reproductive effector. Prolonged exposure can damage nerves, kidneys, and the cardiovascular system. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | 750 °F(isopropanol |
| Explosion Limits: | 2.5-12%(isopropanol) |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic fumes and zirconia dust. |
| Unusual Fire or Explosion Hazards: | Flammable material. Formation of explosive air/dust mixtures is possible. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all ignition sources. Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container in a cool dry place. If container is left open, product may adsorb moisture and carbon dioxide from the atmosphere and release isopropanol vapor. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white xtl. |
| Molecular Weight: | 327.56 (387.67) |
| Melting Point: | no data |
| Boiling Point: | dec. |
| Vapor Pressure: | not applicable |
| Specific Gravity: | no data |
| Odor: | medicine like odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Keep away from moisture, heat and ignition sources including open flame and electrostatic discharge. |
| Incompatibility: | Water, active metals and halogens |
| Decomposition Products: | Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No specific information available on this product. Isopropanol: skin (rbt) draize: mild; eye (rbt) draize: severe; oral (human) TDLo: 223 mg/Kg; oral (human) LDLo: 5272 mg/kg; oral (human) LDLo: 3570 mg/kg; oral (rat) LD50: 5045 mg/kg; inhalation (rat) LC50:16000 ppm/8h. |
| Carcinogenic Effects: | Isopropanol: Tumorigen |
| Mutagenic Effects: | Isopropanol: Possible mutagen |
| Tetratogenic Effects: | Isopropanol: Reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable solids, Organic, N.O.S. |
| Hazard Class (CFR): | 4.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1325 |
| Shipping Name (IATA): | Flammable solid, Organic, N.O.S. |
| Hazard Class (IATA): | 4.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1325 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | Isopropanol (Strong acid process): listed, TSCA, SARA. |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 2/26/2001 |
| Revision Date: | 1/08/2010 |
