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22-2222
Titanium Titanium(IV) (di-i-propoxide)bis[BREW] (99.99+%-Ti) PURATREM
CAS Number:
MDL Number: MFCD01636106
Molecular Formula:  
Molecular Weight:  
Chemical Formula: Ti(OC3H7)2[C×HyC(O)CHC(O)C×Hy]2 (x=3-4, y=2x + 1)
Color and Form: red-orange liq.
Note: 8-11 wt% Ti

Stability: moisture sensitive

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See 08-2012 (page !_!08-2012!_!)

SECTION 1: Product Identification
Chemical Name: Titanium (IV) (di-i-propoxide)bis BREW (99.99+%-Ti) PURATREM
Product Number: 22-2222
CAS Registry Number: not available
Formula: Ti(OC3H7)2[CxHyC(O)CHC(O)CxHy]2 (x=3-4, y=2x + 1)
EINECS Number: none
Chemical Family: metal alkoxide
Synonym: BREW = a mixture of propyl and butyl substituted beta-diketonates
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound not available 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Ingestion, inhalation
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may cause moderate irritation of the gastrointestinal tract, nausea, vomiting, headache, and coma.
Acute Health Effects: The product is a mild irritant. isopropanol is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time.
Chronic Health Effects: No data is available for this product. Isopropanol is a possible mutagen, tumorigen and reproductive effector. Prolonged exposure may damage nerves, kidneys, and the cardiovascular system.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit irritating organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be absorbed into vermiculite or other suitable adsorbent. Sweep up the solid and properly dispose of.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container in a cool dry place. If container is left open, product may adsorb moisture from the atmosphere and release isopropanol vapor.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: red-orange liq.
Molecular Weight: not applicable
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with water
Incompatibility: oxidizing agents
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, soot, and metal oxides and carbonates.
SECTION 11: Toxicological Information
RTECS Data: No information available from the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Not reportable under SARA section 313.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 8/05/2001
Revision Date: 12/13/2011

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