| CAS Number: | 20717-86-6 |
| MDL Number: | MFCD00009861 |
| Molecular Formula: | C9H21ClO3Ti |
| Molecular Weight: | 260.62 |
| Chemical Formula: | TiCl(OC3H7)3 |
| Color and Form: | |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: flash point 72°F, density 1.091
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Chlorotitanium triisopropoxide, 97% |
| Product Number: | 22-0380 |
| CAS Registry Number: | 20717-86-6 |
| Formula: | TiCl(OC3H7)3 |
| EINECS Number: | none |
| Chemical Family: | metal alkoxide |
| Synonym: | Triisopropoxytitanium chloride |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 20717-86-6 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Corrosive. Causes burns. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes |
| Eye Contact: | The hydrochloric acid and the isopropanol released on hydrolysis is severely corrosive to eyes. |
| Skin Contact: | Causes burns to the skin. |
| Inhalation: | Inhalation can lead to burns of the respiratory tract. |
| Ingestion: | Ingestion causes burns to the mouth, throat and esophagus. |
| Acute Health Effects: | Corrosive. Causes burns. Material is extremely destructive to nose, mucous membranes, respiratory tract, skin and eyes. |
| Chronic Health Effects: | No information available on long-term chronic effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 72°F |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic and corrosive hydrochloric acid fumes and titania dust. |
| Unusual Fire or Explosion Hazards: | Flammable. Formation of explosive air/ vapor mixtures is possible. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all ignition sources. Avoid contact with water. Small spills can be mixed with powdered sodium carbonate or powdered limestone and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume hood. Prolonged exposure to the atmosphere will lead to degradation of the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | Material may form a corrosive vapor upon exposure to air. if possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | |
| Molecular Weight: | 260.62 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.091 |
| Odor: | none |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Keep away from moisture, heat and ignition sources including open flame and electrostatic discharge. |
| Incompatibility: | Oxidizing agents |
| Decomposition Products: | Carbon dioxide, carbon monoxide, organic vapors, soot, and metal oxides and carbonates. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable liquids, Corrosive, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | 8 |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 2924 |
| Shipping Name (IATA): | Flammable liquids, Corrosive, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | 8 |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 2924 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Not reportable under SARA section 313. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 8/05/2001 |
| Revision Date: | 12/19/2011 |