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CAS Number: 13801-49-5
Product Catalog
93-4040
Zirconium › Tetrakis(diethylamino)zirconium, 99%| CAS Number: | 13801-49-5 |
| MDL Number: | MFCD00015649 |
| Molecular Formula: | C16H40N4Zr |
| Molecular Weight: | 379.74 |
| Chemical Formula: | Zr[N(CH2CH3)2]4 |
| Color and Form: | yellow liq. |
| Note: |
Stability: moisture sensitive, store cold
Safety: Hazardous
Physical Characteristics: boiling point 112°C/0.1mm, density 1.026
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Tetrakis(diethylamino)zirconium, 99% |
| Product Number: | 93-4040 |
| CAS Registry Number: | 13801-49-5 |
| Formula: | Zr[N(CH2CH3)2]4 |
| EINECS Number: | none |
| Chemical Family: | metal amide complex |
| Synonym: | none |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 13801-49-5 | 100 | 5mg/m3 (as Zr) | 5mg/m3 (as Zr) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Inhalation may cause dizziness and headache. Very irritating to eyes, skin and mucous membranes. Hydrolysis may produce toxic and corrosive diethylamine |
| Primary Routes of Exposure: | Eye, skin ingestion and inhalation |
| Eye Contact: | Causes mild to severe irritation of the eyes. |
| Skin Contact: | Causes mild to severe irritation of the skin. Diethylamine, a hydrolysis product, is alkaline and corrosive. |
| Inhalation: | Irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | Irritating to mouth, throat and stomach. No information available on the physiological effects of ingestion. |
| Acute Health Effects: | Irritation to skin, eyes and mucous membranes. Contact with moisture may produce heat and toxic corrosive diethylamine. |
| Chronic Health Effects: | Inhalation of zirconium compounds as dust may cause pulmonary granulomas. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | dry chemical, carbon dioxide, or foam. |
| Special Fire Fighting Procedures: | If this material is involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may release toxic and irritating fumes. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be absorbed into vermiculite or other suitable adsorbent. Material may begin to hydrolyze forming flammable irritating and noxious fumes. Eliminate all potential ignition sources. Emergency team must be equipped with a self-contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. This product will react with atmospheric moisture and chemically degrade. Transfer material under an inert atmosphere of nitrogen, argon or very dry air. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Work with this product in a well-ventilated area, preferably a fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134 |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | yellow liq. |
| Molecular Weight: | 379.74 |
| Melting Point: | no data |
| Boiling Point: | 112°C/0.1mm |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | fishy odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive. |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with moisture |
| Incompatibility: | water, mineral acids, halogens and oxidizing agents |
| Decomposition Products: | carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and zirconium oxide. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Organometallic substance,Liquid,Water-reactive,Flammable |
| Hazard Class (CFR): | 4.3 |
| Additional Hazard Class (CFR): | 3 |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 3399 |
| Shipping Name (IATA): | Organometallic substance,Liquid,Water-reactive,Flammable |
| Hazard Class (IATA): | 4.3 |
| Additional Hazard Class (IATA): | 3 |
| Packaging Group (IATA): | I |
| UN ID Number (IATA): | UN# 3399 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/29/2001 |
| Revision Date: | 7/22/2011 |
