| CAS Number: | 10170-68-0 |
| MDL Number: | MFCD00013222 |
| Molecular Formula: | C12H24Cl3CrO3 |
| Molecular Weight: | 374.67 |
| Chemical Formula: | CrCl3(C4H8O)3 |
| Color and Form: | purple pwdr. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Chromium(III) chloride tetrahydrofuran adduct, 98% |
| Product Number: | 24-0280 |
| CAS Registry Number: | 10170-68-0 |
| Formula: | C12H24Cl3CrO3 |
| EINECS Number: | none |
| Chemical Family: | metal halide |
| Synonym: | Chromium trichloride tetrahydrofuran adduct |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 10170-68-0 | 100 | 0.5mg/m3 (as Cr) | 0.5mg/m3 (as Cr) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Harmful if swallowed. Corrosive to skin, eyes and respiratory tract. Possible risk of harm to the unborn child, impaired fertility and irreversible effects. Tetrahydrofuran can cause drowsiness. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes |
| Eye Contact: | Dust and vapors cause burns to the eyes and blindness. |
| Skin Contact: | Causes burns to the skin. May cause sensitization through skin contact. |
| Inhalation: | Corrosive to the nose, mucous membranes and respiratory tract. May cause sensitization through inhalation. |
| Ingestion: | Harmful if swallowed. Ingestion may cause damage to the mouth, throat and esophagus. |
| Acute Health Effects: | Corrosive to skin, eyes and respiratory tract. Possible risk of harm to the unborn child. |
| Chronic Health Effects: | Although less toxic than Chromium (VI), chromium (III) chloride may act as a mutagen and reproductive effector. Possible risk of impaired fertility and irreversible effects. In animal studies, tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector. |
| NTP: | Yes |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | no data |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic and corrosive fumes. |
| Unusual Fire or Explosion Hazards: | No unususal fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with sodium bicarbonate, lime or calcium carbonate and swept up. Avoid raising dust. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store material in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | purple powder |
| Molecular Weight: | 374.67 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | ethereal odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with moisture |
| Incompatibility: | water, alcohols, oxidizing agents, oxygen and active metals |
| Decomposition Products: | Chromium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data |
| Mutagenic Effects: | No data |
| Tetratogenic Effects: | No data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Corrosive solid, Acidic, Inorganic, N.O.S. |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | III |
| UN ID Number (CFR): | UN# 3260 |
| Shipping Name (IATA): | Corrosive solid, Acidic, Inorganic, N.O.S. |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | III |
| UN ID Number (IATA): | UN# 3260 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Chromium(III) chloride: Listed in the TSCA inventory |
| SARA (Title 313): | Title compound: See category code N090 for reporting |
| Second Ingredient: | no data |
| Third Ingredient: | no data |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 12/11/2009 |
| Revision Date: | 12/27/2011 |