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CAS Number: 13283-01-7
Product Catalog

74-2350
Tungsten Tungsten(VI) chloride (99.9%-W)
CAS Number: 13283-01-7
MDL Number: MFCD00011463
Molecular Formula: Cl6W
Molecular Weight: 396.57
Chemical Formula: WCl6
Color and Form: purple xtl.
Note:  

Stability: moisture sensitive

Safety: Hazardous

Physical Characteristics: melting point 275°C, boiling point 346.7°C

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SECTION 1: Product Identification
Chemical Name: Tungsten (VI) chloride (99.9%-W)
Product Number: 74-2350
CAS Registry Number: 13283-01-7
Formula: WCl6
EINECS Number: 236-293-9
Chemical Family: metal halide
Synonym: Tungsten hexachloride
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 13283-01-7 100 1mg/m3 (as W - soluble) no data
SECTION 3: Hazards Identification
Emergency Overview: Corrosive to skin and eyes. Material hydrolyzes in contact with moisture releasing toxic and corrosive fumes of hydrogen chloride and aqueous hydrochloric acid.
Primary Routes of Exposure: Contact with skin and eyes. Inhalation of dust.
Eye Contact: Corrosive to the eyes.
Skin Contact: Corrosive to skin.
Inhalation: Harmful by inhalation. Forms hydrogen chloride in the presence of moisture. Inhalation can lead to burning of the respiratory tract.
Ingestion: Harmful if swallowed.
Acute Health Effects: Corrosive to skin, eyes and respiratory tract. Causes eye and skin burns, dyspnea (difficulty breathing) and pulmonary edema.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: None. Material is non-flammable.
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic fumes of hydrogen chloride.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid raising dust.
SECTION 7: Handling and Storage
Handling and Storage: Store solid in a tightly sealed bottle away from moisture. If possible, handle solid in an efficient fume hood. Prolonged exposure to the atmosphere will lead to degradation of the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: The solid may form corrosive vapors. It should be handled in an efficient fume hood.
Respirator: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: purple xtl.
Molecular Weight: 396.57
Melting Point: 275°C
Boiling Point: 346.7°C
Vapor Pressure: no data
Specific Gravity: no data
Odor: pungent odor
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: water and active metals
Decomposition Products: Tungsten oxychloride, hydrogen chloride
SECTION 11: Toxicological Information
RTECS Data: Oral (mouse); LD50: 1.08g/kg. Oral (rat); LD50: 1.8g/kg. Inhalation (rat); TCLo: 43mg/m3. Inhalation (mammal-species unknown); TCLo: 6mg/m3.
Carcinogenic Effects: no data
Mutagenic Effects: Negative data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive Solids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1759
Shipping Name (IATA): Corrosive Solid, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1759
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 6/11/2001
Revision Date: 12/14/2011

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