CAS Number: 603-33-8
Product Catalog

93-8350

Bismuth › Triphenylbismuth, 99%

CAS Number:	603-33-8
MDL Number:	MFCD00014064
Molecular Formula:	C18H15Bi
Molecular Weight:	440.30
Chemical Formula:	(C6H5)3Bi
Color and Form:	white xtl.
Note:	For sale in USA. For other countries contact Strem.

Physical Characteristics: melting point 77-78°C, boiling point dec. 310°C (subl. 100°C/0.2mm), density 1.585

Transportation: For sale in usa only. See MSDS sheet.

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SECTION 1: Product Identification
Chemical Name:	Triphenylbismuth, 99%
Product Number:	93-8350
CAS Registry Number:	603-33-8
Formula:	(C6H5)3Bi
EINECS Number:	210-033-4
Chemical Family:	organobismuth compound
Synonym:	none

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title compound	603-33-8	100	no data	no data

SECTION 3: Hazards Identification
Emergency Overview:	May be irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:	Ingestion, inhalation, eyes
Eye Contact:	May cause mild irritation of the eyes.
Skin Contact:	May cause slight to mild irritation of the skin.
Inhalation:	Inhalation of dust may be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:	May cause gastrointestinal irritation, nausea, vomiting, gingivitis (gum disease), ulcers, diarrhea, malaise, and dermatitis.
Acute Health Effects:	May be irritating to skin, eyes, and respiratory tract. In large doses, bismuth may be toxic causing gingivitis, ulcers, diarrhea, malaise and dermatitis.
Chronic Health Effects:	Can cause metal line on gums, foul breath and mild kidney damage.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	no data
Autoignition Temperature:	no data
Explosion Limits:	no data
Extinguishing Medium:	carbon dioxide or dry powder
Special Fire Fighting Procedures:	If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure self-contained breathing apparatus.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic and corrosive fumes.
Unusual Fire or Explosion Hazards:	No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be absorbed into vermiculite or other suitable adsorbent. Sweep up the material and dispose of properly.

SECTION 7: Handling and Storage
Handling and Storage:	Store the material in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:	To minimize exposure handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	white xtl
Molecular Weight:	440.3
Melting Point:	77-78°C
Boiling Point:	dec.310°C
Vapor Pressure:	(subl. 100°C/.2mm)
Specific Gravity:	1.585
Odor:	none
Solubility in Water:	insoluble

SECTION 10: Stability and Reactivity
Stability:	air and moisture stable
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	none
Incompatibility:	oxidizing agents
Decomposition Products:	carbon monoxide, carbon dioxide, bismuth salts and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	Oral (mouse); LDLo: 320 mg/kg. Intraperitoneal (mouse); LDLo: 250 mg/kg. Intravenous (mouse); LD50: 180 mg/kg.
Carcinogenic Effects:	no data
Mutagenic Effects:	no data
Tetratogenic Effects:	no data

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Non-hazardous
Hazard Class (CFR):	NA
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	NA
UN ID Number (CFR):	NA
Shipping Name (IATA):	Non-hazardous
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	NA

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	1/02/2004
Revision Date:	10/24/2011