| CAS Number: | 7632-00-0 |
| MDL Number: | MFCD00011118 |
| Molecular Formula: | NNaO2 |
| Molecular Weight: | 69.00 |
| Chemical Formula: | NaNO2 |
| Color and Form: | white pwdr. |
| Note: |
Stability: hygroscopic
Safety: Hazardous
Physical Characteristics: melting point 271°C, boiling point 320°C dec., density 2.168
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Sodium nitrite, 97+% (ACS) |
| Product Number: | 93-1162 |
| CAS Registry Number: | 7632-00-0 |
| Formula: | NaNO2 |
| EINECS Number: | 231-555-9 |
| Chemical Family: | inorganic compound |
| Synonym: | Nitrous acid, sodium salt |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 7632-00-0 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Irritating to eyes, skin, and respiratory tract. Toxic by inhalation and if swallowed. May cause heritable genetic damage, harm to the unborn child, and impair fertility. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes. |
| Eye Contact: | Causes irritation, redness and pain. |
| Skin Contact: | Causes irritation, redness and pain. May be absorbed through the skin. |
| Inhalation: | Toxic. Causes irritation to the respiratory tract, and in large amounts, poisoning. |
| Ingestion: | Toxic. Ingestion of as little as 1/2 ounce may cause nitrite poisoning including intense cyanosis, nausea, dizziness, vomiting, collapse, coma, and death. |
| Acute Health Effects: | Irritating to eyes, skin, and respiratory tract. Toxic by inhalation and if swallowed. Nitrite poisoning may cause cyanosis, nausea, dizziness, vomiting, collapse, rapid heart beat, irregular breathing, coma, convulsions, circulatory collapse and death. May cause harm to the unborn child. |
| Chronic Health Effects: | May cause heritable genetic damage and impair fertility. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | no data |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide or dry powder |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire, this material may emit toxic and corrosive fumes of nitrogen oxides. |
| Unusual Fire or Explosion Hazards: | Metal nitrites are oxidizers. Contact with combustible materials can lead to fires and/or explosions. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Do not mix spilled powder with any combustible materials. Sweep up the solid and dilute with water. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry place in a tightly sealed container. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white powder |
| Molecular Weight: | 69 |
| Melting Point: | 271°C |
| Boiling Point: | 320°C dec. |
| Vapor Pressure: | not applicable |
| Specific Gravity: | 2.168 |
| Odor: | none |
| Solubility in Water: | 81.5g/100cc (15°C) |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | hygroscopic |
| Hazardous Polymerization: | No hazardous polymerization |
| Conditions to Avoid: | may burst into flame or explode in contact with organic matter in the presence of heat or friction. |
| Incompatibility: | ammonium salts, cellulose, cyanides, lithium, potassium plus ammonia, sodium thiosulfate, aminoguanide salts, butadiene, reluctant. |
| Decomposition Products: | nitrogen oxides and sodium oxide. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Administration into the eye (rabbit); Standard Draize test: 500 mg/24H. Oral (human); TDLo: 14 mg/kg. Oral (human-man); LDLo: 321 mg/kg. Oral (human-man); TDLo: 1714 ug/kg/70M. Oral (human); LDLo: 71 mg/kg. Oral (human-child); LDLo: 22 mg/kg. Oral (rat); LD50: 180 mg/kg. Inhalation (rat); LC50: 5500 ug/m3/4H. Subcutaneous (rat); LD50: 96600 ug/kg. Intravenous (rat); LD50: 65 mg/kg. Oral (rat); TDLo: 180 mg/kg/8D-I. Oral (rat); TDLo: 2190 gm/kg/2Y-C. Oral (rat); TDLo: 660 mg/kg. Oral (mouse): TDLo: 480mg/Kg. |
| Carcinogenic Effects: | Data available |
| Mutagenic Effects: | Mutagen |
| Tetratogenic Effects: | Reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Very toxic to aquatic organisms. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Sodium nitrite |
| Hazard Class (CFR): | 5.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | III |
| UN ID Number (CFR): | UN# 1500 |
| Shipping Name (IATA): | Sodium nitrite |
| Hazard Class (IATA): | 5.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | III |
| UN ID Number (IATA): | UN# 1500 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound regulated under Sec. 313. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 6/17/2004 |
| Revision Date: | 9/07/2011 |