CAS Number: 598-30-1
Product Catalog

93-0389

Lithium › s-Butyllithium, 12% in cyclohexane (1.4M)

Stability: moisture sensitive, store cold

Safety: Hazardous, pyrophoric

Physical Characteristics: flash point 1°F

Transportation: Boat, truck. See MSDS sheet.

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SECTION 1: Product Identification
Chemical Name:	s-Butyllithium, 12% in cyclohexane (1.4M)
Product Number:	93-0389
CAS Registry Number:	598-30-1
Formula:	C4H9Li
EINECS Number:	209-927-7
Chemical Family:	metal alkyl
Synonym:	sec-butyllithium

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title compound	598-30-1	20	no data	no data
cyclohexane	110-82-7	80	200ppm	1050mg/m3

SECTION 3: Hazards Identification
Emergency Overview:	Extremely flammable liquid that causes burns to skin, eyes and respiratory tract. Inhalation of vapors may depress central nervous system causing dizziness, headache, unconsciousness and coma.
Primary Routes of Exposure:	Ingestion, inhalation, eyes, skin
Eye Contact:	Causes burns to the eyes. May cause severe eye damage.
Skin Contact:	Contact with skin causes thermal and chemical burns, redness and pain.
Inhalation:	Inhalation of vapors may depress the central nervous system causing nausea, headache, dizziness, unconsciousness and coma. Harmful if inhaled.
Ingestion:	Causes burns.Ingestion may cause lung damage, nausea, vomiting and headache.
Acute Health Effects:	Causes burns to skin, eyes and respiratory tract. May cause lung damage if aspirated into the lungs. Lithium salts are toxic to the central nervous system. Harmful: danger of serious damage to health by prolonged exposure through inhalation.
Chronic Health Effects:	Lithium salts are toxic to the central nervous system and on repeated ingestion may damage kidneys and act as a teratogen. Repeated skin exposure to cyclohexane causes defatting and dermatitis. Cyclohexane may cause liver and kidney damage.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	1°F
Autoignition Temperature:	245°C
Explosion Limits:	LEL (1.3%) UEL (8.0%)
Extinguishing Medium:	carbon dioxide or dry powder
Special Fire Fighting Procedures:	Fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing apparatus.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit caustic and corrosive fumes.
Unusual Fire or Explosion Hazards:	Pyrophoric material. May ignite spontaneously on contact with air.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	The material may ignite spontaneously in air. Burning material may release caustic fumes. Small spills can be absorbed into vermiculite, diatomaceous earth, or other suitable chemical absorbent

SECTION 7: Handling and Storage
Handling and Storage:	Handle and store the material under an inert atmosphere of dry nitrogen or argon. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses. When handling this substance wear a face shield as added protection.
Skin Protection:	Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:	It is imperative that this product is handled in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance 29 CFR 1910.134.
Additional Protection:	A full face shield and rubber apron is recommended

SECTION 9: Physical and Chemical Properties
Color and Form:	colorless to light yellow liquid
Molecular Weight:	64.05
Melting Point:	no data
Boiling Point:	81°C (cyclohexane)
Vapor Pressure:	79mm (20°C)
Specific Gravity:	no data
Odor:	chloroform-like
Solubility in Water:	reacts vigorously with water

SECTION 10: Stability and Reactivity
Stability:	moisture sensitive, pyrophoric (store cold)
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	contact with moist air, heat and ignition sources.
Incompatibility:	water, air, alcohols, active metals, oxidizing agents and halogens.
Decomposition Products:	carbon monoxide, carbon dioxide, lithium oxide and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:	No information available on title compound. For cyclohexane--Standard Draize test (rabbit); 1548mg/2D (intermittent). Oral (rat); LD50: 12705mg/kg. Oral (mouse); LD50: 813mg/kg. Inhalation (mouse); LCLo: 70gm/m3/2H. Oral (rabbit); LDLo: 5500mg/kg. Inhalation (rabbit); LCLo: 89600mg/m3/1H. Administration onto the skin (rabbit); LD: >180g/kg. DNA adduct (E.Coli); 10umol/L.
Carcinogenic Effects:	no data
Mutagenic Effects:	Insufficient data (cyclohexane)
Tetratogenic Effects:	no data

SECTION 12: Ecological Information
Ecological Information:	Avoid release into the environment. Very toxic to aqatic organisms. May cause long-term adverse effects in the aquatic environment.

SECTION 13: Disposal Considerations
Disposal:	Dispose of this material according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Organometallic substance,Liquid,Pyrophoric,Water-reactive
Hazard Class (CFR):	4.2
Additional Hazard Class (CFR):	4.3
Packaging Group (CFR):	I
UN ID Number (CFR):	UN# 3394
Shipping Name (IATA):	Forbidden
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	UN# 3394

SECTION 15: Regulatory Information
TSCA:	Listed on the TSCA inventory
SARA (Title 313):	Title compound not listed
Second Ingredient:	Listed in the TSCA inventory. Regulated under SARA 313.
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	6/17/2004
Revision Date:	12/20/2011