| CAS Number: | 73491-36-8 |
| MDL Number: | MFCD00061608 |
| Molecular Formula: | CF3O3STl |
| Molecular Weight: | 353.45 |
| Chemical Formula: | TlSO3CF3 |
| Color and Form: | white pwdr. |
| Note: |
Stability: hygroscopic
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Thallium (I) trifluoromethanesulfonate, 99% (Thallium triflate) |
| Product Number: | 81-8500 |
| CAS Registry Number: | 73491-36-8 |
| Formula: | TlSO3CF3 |
| EINECS Number: | none |
| Chemical Family: | metal triflate compounds |
| Synonym: | Thallium triflate |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 73491-36-8 | 100 | 0.1 mg/m3 (sol Tl) | 0.1 mg/m3 (sol Tl) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Thallium compounds are very toxic by inhalation and if swallowed. Irritating to skin, eyes and respiratory tract. Danger of cumulative effects. |
| Primary Routes of Exposure: | Ingestion, skin, inhalation of dust. |
| Eye Contact: | Causes severe irritation to the eyes. |
| Skin Contact: | Causes severe irritation of the skin causing redness, pain, itching, |
| Inhalation: | Very toxic by inhalation. Irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | Very toxic if swallowed. Ingestion may result in swelling of the feet and legs, mental confusion, paralysis, angina-like pains. |
| Acute Health Effects: | Very toxic by inhalation and if swallowed. Acute poisoning results in pain of the extremities, fever, nausea and vomiting, jumbled speech, tremors, convulsions, kidney failure, and pulmonary edema. |
| Chronic Health Effects: | Danger of cumulative effects. Prolonged exposure to thallium compounds has been reported to lead to discoloration of the hair, which later falls out, joint pain, loss of appetite, fatigue, severe pain in the legs, albuminuria, and optic neuritis. Possible mutagen. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | none required |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | This material may emit toxic fumes of thallium, hydrogen fluoride, carbonyl fluoride, and sulfur dioxide. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be neutralized with sodium carbonate, sodium bicarbonate or lime. The solids can then be swept up and properly disposed of. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store material in a tightly sealed bottle away from moisture. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with a glove manufacturer to determine the proper type of glove. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white pwdr. |
| Molecular Weight: | 353.45 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | none |
| Solubility in Water: | decomposes in water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | hygroscopic |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | Active metals |
| Decomposition Products: | carbonyl fluoride, carbon monoxide, organic fumes, hydrogen fluoride, sulfur dioxide, and metal salts. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Toxic to aquatic organisms . May cause long-term adverse effects to the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Thallium compounds, N.O.S. |
| Hazard Class (CFR): | 6.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1707 |
| Shipping Name (IATA): | Thallium compound, N.O.S. |
| Hazard Class (IATA): | 6.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1707 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound: See category code N760 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 12/06/2001 |
| Revision Date: | 8/02/2011 |