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CAS Number: 20816-12-0
Product Catalog

76-2952
Osmium Osmium(VIII) oxide, 4% in water
CAS Number: 20816-12-0
MDL Number: MFCD00011150
Molecular Formula: O4Os
Molecular Weight:  
Chemical Formula: OsO4
Color and Form: colorless liq.
Note:  

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Osmium(VIII) oxide, 4% in water
Product Number: 76-2952
CAS Registry Number: 20816-12-0
Formula: OsO4
EINECS Number: 244-058-7
Chemical Family: metal oxide
Synonym: Osmic acid
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 20816-12-0 4 0.0002ppm (as OsO4) 0.002mg/m3 (as Os)
water 7732-18-5 96
SECTION 3: Hazards Identification
Emergency Overview: Very toxic by inhalation, in contact with skin and if swallowed. Causes permanent damage to the eyes. Causes burns to skin and respiratory tract.
Primary Routes of Exposure: Ingestion, inhalation, eyes, skin
Eye Contact: Causes severe damage to eye tissue. Exposure to vapor can cause blindness.
Skin Contact: Very toxic in contact with skin. Causes caustic burns of the skin.
Inhalation: Very toxic by inhalation. Inhalation leads to structural and functional changes to the trachea.
Ingestion: Very toxic if swallowed.
Acute Health Effects: Very toxic by inhalation, in contact with skin and if swallowed. Damage to the eyes. Causes burns to skin, nose, mucous membranes and respiratory tract.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: none
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit irritating fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: If released outside an area of adequate ventilation, evacuate the area. Enter only if equipped with a self-contained breathing apparatus. Absorb liquid in vermiculite or other suitable adsorbent.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Keep away from heat and moisture. Handle only in a efficient fume hood.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Adequate ventilation is essential. Vapor is extremely hazardous. Handle material only in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless liquid
Molecular Weight: 254.20
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: material is a water solution
SECTION 10: Stability and Reactivity
Stability: air and moisture-stable liquid
Hazardous Polymerization: none
Conditions to Avoid: Oxidizer. Avoid mixing or heating with combustible materials.
Incompatibility: Reducing agents, alcohols, alkenes, chlorinated hydrocarbons
Decomposition Products: osmium tetroxide vapors, osmium metal
SECTION 11: Toxicological Information
RTECS Data: For pure osmium tetroxide: Inhalation (human); TCLo: 133ug/m3. Inhalation (rat); LCLO: 40ppm/4H. Intraperitoneal (rat); LD50: 14100ug/m3. Oral (mouse): 162mg/kg. Inhalation (mouse); LCLo: 40ppm/4H. Intraperitoneal (mouse); LD50: 13500ug/m3. Inhalation (rabbit); LCLo: 1316mg/m3/30M. Intratesticular (rat); TDLo: 20336/ug/m3. Subcutaneous (mouse); TDLO: 20336ug/kg. Lacrymator. Damage to eyes. Inhalation leads to structural and functional changes to the trachea and bronchi. Paternal effects - testes, epididymis, genetic material. Inhalation can lead to coma in test animals.
Carcinogenic Effects: No data available
Mutagenic Effects: Suspected mutagen
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Osmium tetroxide
Hazard Class (CFR): 6.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): I
UN ID Number (CFR): UN# 2471
Shipping Name (IATA): Osmium tetroxide
Hazard Class (IATA): 6.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): I
UN ID Number (IATA): UN# 2471
SECTION 15: Regulatory Information
TSCA: listed on the TSCA inventory
SARA (Title 313): Repeortable under SARA 313.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 9/12/1999
Revision Date: 8/01/2011

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