| CAS Number: | 2767-54-6 |
| MDL Number: | MFCD00000052 |
| Molecular Formula: | C6H15BrSn |
| Molecular Weight: | 285.78 |
| Chemical Formula: | (C2H5)3SnBr |
| Color and Form: | colorless liq. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: melting point -13.5°C, boiling point 73-74°C/2.9 mm, flash point 211°F, density 1.630
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Triethyltin bromide, min. 97% |
| Product Number: | 50-3000 |
| CAS Registry Number: | 2767-54-6 |
| Formula: | (C2H5)3SnBr |
| EINECS Number: | 220-443-5 |
| Chemical Family: | organotin compound |
| Synonym: | Bromotriethylstannane, Triethylstannium bromide |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 2767-54-6 | 100 | 0.1mg/m3 | 0.1mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Toxic by inhalation, in contact with skin and if swallowed. Irritating to skin, eyes and respiratory tract. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes |
| Eye Contact: | Causes severe irritation to the eyes. May cause blindness. |
| Skin Contact: | Toxic in contact with skin. Prolonged contact will cause redness and severe irritation to the skin. |
| Inhalation: | Toxic by inhalation. Irritating to the nose, mucous membranes and respiratory tract. High doses may cause long term neurological damage. |
| Ingestion: | Toxic if swallowed. Delayed and permanent psycho-neurologic disturbances; impairment of vision, unsteadiness, nausea and vomiting. |
| Acute Health Effects: | Irritating to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause delayed poisoning (4 days) with cerebral edema causing damage to the central nervous system. |
| Chronic Health Effects: | Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory system, central nervous system, liver, kidneys, urinary tract, and blood. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 211°F |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, foam or dry powder |
| Special Fire Fighting Procedures: | Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | carbon monoxide, carbon dioxide, soot, organic fumes and tin compounds. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite, ground limestone, sodium carbonate or other suitable noncombustible adsorbent and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Work with this product in a well-ventilated area, preferably a fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liq. |
| Molecular Weight: | 285.78 |
| Melting Point: | -13.5°C |
| Boiling Point: | 73-74°C/2.9 mm |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.63 |
| Odor: | irritating odor |
| Solubility in Water: | slightly soluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | strong oxidizing agents and halogens |
| Decomposition Products: | carbon dioxide, carbon monoxide, hydrogen bromide, tin oxide, and organic fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Inhalation (mouse); LCLo: 1640 mg/m3/10M. Oral (rat); TDLo: 6 mg/kg/6D-I. Oral (rat); TDLo: 28 mg/kg/2W-I. Oral (rat); TDLo: 18410 ug/kg/28D-C. Oral (rat); TDLo: 63 mg/kg/3W-C. Intraperitoneal (rat); TDLo: 6 mg/kg. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | Insufficient data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Very toxic to the aquatic environment. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to federal, state, and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Organotin compounds, Liquid, N.O.S. |
| Hazard Class (CFR): | 6.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 2788 |
| Shipping Name (IATA): | Organotin compound, Liquid, N.O.S. |
| Hazard Class (IATA): | 6.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 2788 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/02/2002 |
| Revision Date: | 8/16/2011 |