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45-0177
Rhodium › (+)-2,3-Bis[(2S,5S)-2,5-dimethylphospholanyl]-1-methyl-1H-pyrrole-2,5-dione(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% [catASium® MN(S)Rh]| CAS Number: | |
| MDL Number: | MFCD09763650 |
| Molecular Formula: | C25H39BF4NO2P2Rh |
| Molecular Weight: | 637.24 |
| Chemical Formula: | Rh(C8H12)(C17H27NO2P2)+BF4- |
| Color and Form: | red orange pwdr. |
| Note: | Optical purity: 95% Sold in collaboration with EVONIK for research purposes only. Patent WO 03084971. |
Stability: air sensitive
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | (+)-2,3-Bis[(2S,5S)-2,5-dimethylphospholanyl]-1-methyl-1H-pyrrole-2,5-dione( 1,5-cyclooctadiene)rhodium (I) tetrafluoroborate, min. 98% [catASium® MN(S)Rh] |
| Product Number: | 45-0177 |
| CAS Registry Number: | not available |
| Formula: | Rh(C8H12)(C16H25NO2P2)+BF4- |
| EINECS Number: | none |
| Chemical Family: | organometallic complex |
| Synonym: | (1,5-cyclooctadiene)-(+)-2,3-Bis[(2S,5S)-2,5-dimethylphospholanyl]maleimiderhodium (I) tetrafluoroborate |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | not available | 100 | 1mg/m3 (as Rh) | 0.1mg/m3 (as Rh) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Irritating to skin and eyes. Dust is irritating to respiratory tract.May be harmful if swallowed. |
| Primary Routes of Exposure: | Ingestion ,inhalation of dust, skin, eyes |
| Eye Contact: | Causes slight to mild irritation of the eyes. |
| Skin Contact: | Causes slight to mild irritation of the skin. |
| Inhalation: | Irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | No specific information available on the physiological effects of ingestion. May be harmful if swallowed. |
| Acute Health Effects: | Irritating to skin, eyes and respiratory tract. |
| Chronic Health Effects: | Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | no data |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic and metal oxide fumes. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazard. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite or sodium carbonate and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | The material will degrade on prolonged exposure to air. Store under an inert atmosphere of nitrogen or argon. Keep bottle tightly sealed and away from heat and moisture. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | red-orange powder |
| Molecular Weight: | 637.24 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | not determined |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with air. This material may degrade on prolonged exposure to air and moisture. |
| Incompatibility: | strong oxidizing agents and halogens |
| Decomposition Products: | carbon dioxide, carbon monoxide, phosphorus pentoxide, organic fumes and fluorinated by-products. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | no data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to federal, state, and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 7/01/2004 |
| Revision Date: | 8/03/2010 |
