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CAS Number: 114615-82-6
Product Catalog

44-7850
Ruthenium Tetrapropylammonium perruthenate, min. 97% TPAP
CAS Number: 114615-82-6
MDL Number: MFCD00074914
Molecular Formula: C12H28NO4Ru
Molecular Weight: 351.43
Chemical Formula: (C3H7)4N+RuO4-
Color and Form: green xtl.
Note:  

Stability: store cold

Safety: Hazardous

Physical Characteristics: melting point 165°C (dec.)

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SECTION 1: Product Identification
Chemical Name: Tetrapropylammonium perruthenate, min. 97% TPAP
Product Number: 44-7850
CAS Registry Number: 114615-82-6
Formula: (C3H7)4NRuO4
EINECS Number: none
Chemical Family: Alkylammonium salt
Synonym: TPAP
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 114615-82-6 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Ingestion
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Effects: Irritating to skin, eyes and respiratory tract.
Chronic Health Effects: No information available on long-term chronic effects. As a strong oxidant anion, and by analogy to similar salts of other elements, one might expect chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: water, carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards: Oxidizing solid. Rapid heating may cause this compound to explode. Dust may form an explosive mixture with air.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a sealed container. Keep away from heat and moisture.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: green xtl.
Molecular Weight: 351.43
Melting Point: 165°C (dec)
Boiling Point: none
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Rapid heating. Concentrated oxidizing acids may produce toxic volatile ruthenium tetroxide.
Incompatibility: nitric acid, perchloric acid, chlorine, reducing agents and combustible powders.
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, and ruthenium oxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Oxidizing Solid, N.O.S.
Hazard Class (CFR): 5.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN #1479
Shipping Name (IATA): Oxidizing Solid, N.O.S.
Hazard Class (IATA): 5.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN #1479
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 2/26/2001
Revision Date: 8/03/2011

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