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CAS Number: 15629-92-2
Product Catalog

28-0080
Nickel › 1,3-Bis(diphenylphosphino)propane nickel(II) chloride, 99%
CAS Number: 15629-92-2
MDL Number: MFCD00015318
Molecular Formula: C27H26Cl2NiP2
Molecular Weight: 542.08
Chemical Formula: [(C6H5)2PCH2CH2CH2P(C6H5)2]NiCl2
Color and Form: red xtl.
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SECTION 1: Product Identification
Chemical Name: 1,3-Bis(diphenylphosphino)propane nickel (II) chloride, 99%
Product Number: 28-0080
CAS Registry Number: 15629-92-2
Formula: [(C6H5)2PCH2CH2CH2P(C6H5)2]NiCl2
EINECS Number: None
Chemical Family: metal-phosphine complexes
Synonym: 1,3-Bis(diphenylphosphano)propane nickel (II) chloride,
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 15629-92-2 100 0.2mg/m3 (as Ni) 1mg/m3 (as Ni)
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. Ingestion of nickel salts may cause intestinal disorders, convulsions, and asphyxia. May cause cancer.
Primary Routes of Exposure: Ingestion, Inhalation of dust.
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin. Prolonged contact with nickel salts may lead to dermatitis.
Inhalation: Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Effects: Irritating to skin, eyes and respiratory tract. Ingestion may cause intestinal disorders, convulsions, asphyxia, sensitization dermatitis, allergic asthma, and pneumonitis.
Chronic Health Effects: Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause cancer.
NTP: Yes
IARC: Yes
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic and corrosive fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry place in a tightly sealed container.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: red xtl.
Molecular Weight: 542.08
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: oxidizing agents
Decomposition Products: carbon monoxide, carbon dioxide, nickel oxide, phosphorus pentoxide and organic fumes.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: Carcinogen (as Ni)
Mutagenic Effects: No data
Tetratogenic Effects: No data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound: See category code N495 for reporting.
Second Ingredient: None
Third Ingredient: None
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 4/12/2002
Revision Date: 8/15/2011

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