CAS Number: 166172-63-0
Product Catalog

26-0965

Iron › (R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi-3,5-xylylphosphine, min. 97%

CAS Number:	166172-63-0
MDL Number:	MFCD03426992
Molecular Formula:	C44H36F12FeP2
Molecular Weight:	910.57
Chemical Formula:	C44H36F12FeP2
Color and Form:	orange pwdr.
Note:	Sold in collaboration with Solvias for research purposes only. Solvias Josiphos Ligand Kit component.

Physical Characteristics: spec. rotation -280° ±10° (c 0.5, CHCl3)

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SECTION 1: Product Identification
Chemical Name:	(R)-(-)-1-{(S)-2-[Bis(3,5-di-trifluoromethylphenyl)phosphino]ferrocenyl}ethyldi- 3,5-xylylphosphine, min. 97%
Product Number:	26-0965
CAS Registry Number:	166172-63-0
Formula:	C44H36F12FeP2
EINECS Number:	None
Chemical Family:	organophosphine ligand
Synonym:	None

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	166172-63-0	100	2.5mg/m3 (as F)	2.5mg/m3 (as F)

SECTION 3: Hazards Identification
Emergency Overview:	Irritating to skin, and eyes. May be irritating to the respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:	Ingestion, eyes
Eye Contact:	Causes slight to mild irritation of the eyes.
Skin Contact:	Causes slight to mild irritation of the skin.
Inhalation:	May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:	No information available on the physiological effects of ingestion.
Acute Health Effects:	Irritating to skin and eyes. May be irritating to the respiratory tract.
Chronic Health Effects:	Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure and kidney and liver damage.
NTP:	No
IARC:	No
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	not applicable
Autoignition Temperature:	none
Explosion Limits:	none
Extinguishing Medium:	carbon dioxide, foam or dry powder
Special Fire Fighting Procedures:	If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Unusual Fire or Explosion Hazards:	No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.

SECTION 7: Handling and Storage
Handling and Storage:	Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear protective clothing and gloves.
Ventilation:	Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	orange pwdr.
Molecular Weight:	910.57
Melting Point:	no data
Boiling Point:	no data
Vapor Pressure:	no data
Specific Gravity:	no data
Odor:	none
Solubility in Water:	Insoluble

SECTION 10: Stability and Reactivity
Stability:	air and moisture stable
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	exposure to oxygen, contact with strong oxidizing agents
Incompatibility:	Oxidizing agents and halogens
Decomposition Products:	carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, fluoroorganics, and iron oxide.

SECTION 11: Toxicological Information
RTECS Data:	No information available in the RTECS files.
Carcinogenic Effects:	No data
Mutagenic Effects:	No data
Tetratogenic Effects:	No data

SECTION 12: Ecological Information
Ecological Information:	No information available

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Non-hazardous
Hazard Class (CFR):	NA
Additional Hazard Class (CFR):	NA
Packaging Group (CFR):	NA
UN ID Number (CFR):	NA
Shipping Name (IATA):	Non-hazardous
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	NA

SECTION 15: Regulatory Information
TSCA:	Not listed in the TSCA inventory.
SARA (Title 313):	Title compound not listed.
Second Ingredient:	None
Third Ingredient:	None

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	3/20/2002
Revision Date:	12/23/2011