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CAS Number: 19559-06-9
Product Catalog
23-4350
Vanadium › Vanadium(III) chloride tetrahydrofuran adduct| CAS Number: | 19559-06-9 |
| MDL Number: | MFCD00145515 |
| Molecular Formula: | C12H24Cl3O3V |
| Molecular Weight: | 157.30 |
| Chemical Formula: | VCl3(C4H8O)2η3 |
| Color and Form: | red xtl. |
| Note: |
Stability: moisture sensitive, store cold
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Vanadium (III) chloride tetrahydrofuran adduct |
| Product Number: | 23-4350 |
| CAS Registry Number: | 19559-06-9 |
| Formula: | VCl3(C4H8O)2-3 |
| EINECS Number: | none |
| Chemical Family: | metal halide |
| Synonym: | Vanadium trichloride tetrahydrofuran adduct |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 19559-06-9 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Corrosive to skin and eyes. May release toxic and corrosive fumes of hydrogen chloride and aqueous hydrochloric acid. Tetrahydrofuran can cause drowsiness and unconsciousness. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes |
| Eye Contact: | Severe corrosive to the eyes. Exposure can lead to permanent eye damage. |
| Skin Contact: | Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation. |
| Inhalation: | Inhalation of tetrahydrofuran vapor may cause coughing, nausea, dizziness, headache, drowsiness, and unconsciousness. |
| Ingestion: | Ingestion of tetrahydrofuran or hydrogen chloride may cause gastrointestinal and respiratory irritation. |
| Acute Health Effects: | Inhalation of vapor induces drowsiness and may cause coughing, chest pains, difficulty in breathing, nausea, dizziness, headache and unconsciousness. Hydrogen chloride can cause pulmonary edema. |
| Chronic Health Effects: | In animal studies tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic fumes of hydrogen chloride, carbon monoxide, carbon dioxide, and organic fumes. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Avoid raising dust. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store solid in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | The solid may form corrosive vapors. It should be handled in an efficient fume hood. |
| Respirator: | If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | red xtl. |
| Molecular Weight: | 157.3 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | pungent odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with moisture |
| Incompatibility: | Water, alcohols, oxidizing agents, oxygen and active metals |
| Decomposition Products: | Vanadium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | no data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Corrosive solids, N.O.S. |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1759 |
| Shipping Name (IATA): | Corrosive solid, N.O.S. |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1759 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | See category code N770 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 6/11/2001 |
| Revision Date: | 8/01/2011 |
