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CAS Number: 13476-99-8
Product Catalog

23-2250
Vanadium › Vanadium(III) acetylacetonate, 98%
CAS Number: 13476-99-8
MDL Number: MFCD00000033
Molecular Formula: C15H21O6V
Molecular Weight: 348.27
Chemical Formula: V(CH3COCHCOCH3)3
Color and Form: brown xtl.
Note:  

Stability: air sensitive

Safety: Hazardous

Physical Characteristics: melting point 178°C, boiling point subl. (170°C/0.05mm)

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SECTION 1: Product Identification
Chemical Name: Vanadium (III) acetylacetonate, 98%
Product Number: 23-2250
CAS Registry Number: 13476-99-8
Formula: V(CH3COCHCOCH3)3
EINECS Number: 236-759-1
Chemical Family: metal beta-diketonate complexes
Synonym: Tris(2,4-pentanedionato)vanadium
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 13476-99-8 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Toxic if swallowed.
Primary Routes of Exposure: Ingestion
Eye Contact: May cause slight to mild irritation of the eyes.
Skin Contact: May cause slight to mild irritation of the skin.
Inhalation: (If dust) May be irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No information on the physiological effects of ingestion.
Acute Health Effects: May be irritating to skin, eyes and respiratory tract. Toxic if swallowed.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store under argon in a tightly sealed container in a dry place. If container is left open, air and moisture will degrade this material.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: brown xtl.
Molecular Weight: 348.27
Melting Point: 178°C
Boiling Point: subl. (170°C/0.05mm)
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air and moisture sensitive solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: exposure to moisture
Incompatibility: strong oxidizing agents
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Toxic solids, Organic, N.O.S.
Hazard Class (CFR): 6.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): III
UN ID Number (CFR): UN# 2811
Shipping Name (IATA): Toxic solid, Organic, N.O.S.
Hazard Class (IATA): 6.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): III
UN ID Number (IATA): UN# 2811
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): See category code N770 for reporting.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 12/28/2000
Revision Date: 8/03/2011

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