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CAS Number: 18039-90-2
Product Catalog

22-3500
Titanium › Trichlorotris(tetrahydrofuran)titanium(III), min. 97%
CAS Number: 18039-90-2
MDL Number: MFCD01631276
Molecular Formula: C12H24Cl3O3Ti
Molecular Weight: 370.56
Chemical Formula: TiCl3(C4H8O)3
Color and Form: pale blue xtl.
Note:  

Stability: air sensitive, moisture sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Trichlorotris(tetrahydrofuran)titanium(III), min. 97%
Product Number: 22-3500
CAS Registry Number: 18039-90-2
Formula: TiCl3(C4H8O)3
EINECS Number: none
Chemical Family: metal halide
Synonym: Titanium (III) chloride, tetrahydrofuran adduct
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 18039-90-2 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. Material hydrolyzes in contact with moisture releasing toxic and corrosive fumes of hydrogen chloride.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes irritation to the eyes.
Skin Contact: Causes irritation to the skin.
Inhalation: Forms hydrogen chloride in the presence of moisture. Inhalation leads to irritation of the respiratory tract.
Ingestion: No information is available on the physiological effects of ingestion.
Acute Health Effects: Irritating to skin, eyes, mucous membranes and respiratory tract.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: none
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic fumes.
Unusual Fire or Explosion Hazards: Flammable solid. No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed bottle, preferably under an inert atmosphere. If possible, handle material in an efficient fume hood. Prolonged exposure to the atmosphere will lead to degradation of the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If possible, handle the material in an efficient fume hood.
Respirator: No respirator is required when handling this material unless large volumes are handled in a poorly ventilated area.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: pale blue crystal
Molecular Weight: 370.56
Melting Point: no data
Boiling Point: decomposes
Vapor Pressure: no data
Specific Gravity: no data
Odor: may have a strong acidic odor.
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: Air and moisture-sensitive solid
Hazardous Polymerization: none
Conditions to Avoid: material may absorb water from the atmosphere on prolonged exposure.
Incompatibility: water, alcohols, reactive metals
Decomposition Products: hydrogen chloride, titanium oxide, and organic vapors.
SECTION 11: Toxicological Information
RTECS Data: No specific information available from the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Flammable solids, Organic, N.O.S.
Hazard Class (CFR): 4.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1325
Shipping Name (IATA): Flammable solid, Organic, N.O.S.
Hazard Class (IATA): 4.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1325
SECTION 15: Regulatory Information
TSCA: not listed in the TSCA inventory
SARA (Title 313): not reportable under SARA Title 13
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 3/07/2000
Revision Date: 8/03/2011

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