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CAS Number: 12003-13-3
Product Catalog
22-1180
Titanium › Titanium(III) chloride, Al reduced, 98+%| CAS Number: | 12003-13-3 |
| MDL Number: | MFCD00083104 |
| Molecular Formula: | Cl3Ti |
| Molecular Weight: | 198.72 |
| Chemical Formula: | TiCl3·1/3AlCl3 |
| Color and Form: | purple xtl. |
| Note: |
Stability: air sensitive, moisture sensitive
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Titanium (III) chloride, Al reduced, 98+% |
| Product Number: | 22-1180 |
| CAS Registry Number: | 12003-13-3 |
| Formula: | TiCl3.1/3AlCl3 |
| EINECS Number: | 234-421-8 |
| Chemical Family: | metal halide |
| Synonym: | Titanium trichloride |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 12003-13-3 | 77 | no data | no data |
| aluminum chloride | 7446-70-0 | 23 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Severe irritant to skin and eyes. Material hydrolyzes in contact with moisture releasing toxic and corrosive fumes of hydrogen chloride and aqueous hydrochloric acid. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes |
| Eye Contact: | Corrosive to the eyes. |
| Skin Contact: | Causes burns to the skin. |
| Inhalation: | Forms hydrogen chloride in the presence of moisture. Inhalation will lead to burns of the respiratory tract. |
| Ingestion: | Ingestion is unlikely due to pungent choking odor. No information is available on the acute physiological effects of ingestion. |
| Acute Health Effects: | Corrosive to skin, eyes and respiratory tract and causes eye, skin burns, dyspnea (breathing difficulty), and pulmonary edema. |
| Chronic Health Effects: | No information available on long-term chronic effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | None. Material is non-flammable. |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic fumes of hydrogen chloride. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams will require self-contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store solid in a tightly sealed container away from air and moisture. Handle in a fume hood under an inert atmosphere. Prolonged exposure to the atmosphere may degrade the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | The solid may form corrosive vapors. It should be handled in an efficient fume hood. |
| Respirator: | If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | purple xtl. |
| Molecular Weight: | 198.72 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | pungent odor |
| Solubility in Water: | Reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air sensitive, moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with air or moisture |
| Incompatibility: | Water, alcohols, oxidizing agents, oxygen and active metals |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | no data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Titanium trichloride, mixtures |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 2869 |
| Shipping Name (IATA): | Titanium trichloride, mixture |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 2869 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 6/11/2001 |
| Revision Date: | 8/01/2011 |
