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CAS Number: 1271-19-8
Product Catalog
22-0200
Titanium › Bis(cyclopentadienyl)titanium dichloride, 99+% (Titanocene dichloride)| CAS Number: | 1271-19-8 |
| MDL Number: | MFCD00003723 |
| Molecular Formula: | C10H10Cl2Ti |
| Molecular Weight: | 249.00 |
| Chemical Formula: | (C5H5)2TiCl2 |
| Color and Form: | red xtl. |
| Note: |
Stability: moisture sensitive
Physical Characteristics: melting point 289-291°C
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Bis(cyclopentadienyl)titanium dichloride, 99+% (Titanocene dichloride) |
| Product Number: | 22-0200 |
| CAS Registry Number: | 1271-19-8 |
| Formula: | (C5H5)2TiCl2 |
| EINECS Number: | none |
| Chemical Family: | metallocene |
| Synonym: | Dichlorobiscyclopentadienyl titanium, Titanocene dichloride |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 1271-19-8 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Irritating to skin, eyes, and respiratory tract. With moisture may liberate irritating fumes of hydrogen chloride. Possible risk of irreversible effects and harm to the unborn child. |
| Primary Routes of Exposure: | Skin, eyes, inhalation |
| Eye Contact: | Dust and vapors cause moderate to irritation of the eyes. |
| Skin Contact: | Causes moderate irritation of the skin. |
| Inhalation: | Inhalation of dust or fumes causes irritation to the nose, mucous membranes and respiratory tract. |
| Ingestion: | No information is available on the physiological effects of ingestion. |
| Acute Health Effects: | Exposure to moisture slowly produces hydrochloric acid. Irritating to skin, eyes and respiratory tract. Possible risk of harm to the unborn child. |
| Chronic Health Effects: | Possible risk of irreversible effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | none |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | carbon dioxide, dry powder or foam. |
| Special Fire Fighting Procedures: | If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure self-contained breathing apparatus. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic fumes. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with calcium carbonate, sodium bicarbonate or other appropriate acid neutralizing non combustible solid and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | The material will degrade on prolonged exposure to moisture. Keep bottle tightly sealed and away from heat and light. Handle in a dry atmosphere. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | No respirator is required when handling this material. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | red xtl. |
| Molecular Weight: | 249 |
| Melting Point: | 289-291°C |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | none |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | No hazardous polymerization. |
| Conditions to Avoid: | exposure to moisture |
| Incompatibility: | water, strong oxidizing agents |
| Decomposition Products: | carbon monoxide, carbon dioxide, hydrochloric acid, organic fumes and titanium oxide. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Intraperitoneal (rat); LD50: 25 mg/kg. Intraperitoneal (mouse); LD50: 60 mg/kg. Oral (rat); TDLo: 6 gm/kg/14D-I. Oral (rat); TDLo: 26 gm/kg/2Y-I. Intramuscular (rat); TDLo: 720 mg/kg/2Y-I. Intramuscular (rat); TD: 900 mg/kg/2Y-I. Intraperitoneal (mouse); TDLo: 30 mg/kg. Bacteria-Salmonella typhimurium: Mutation in microorganisms: 100 ug/plate. Rat embryo; Morphological transformation: 2960 ug/L. Mouse Fibroblast; Morphological transformation: 800 ug/L. Hamster embryo; Morphological transformation: 100 ug/L. |
| Carcinogenic Effects: | Tumorigen |
| Mutagenic Effects: | Possible mutagen |
| Tetratogenic Effects: | Possible reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 2/09/2004 |
| Revision Date: | 8/22/2011 |
