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CAS Number: 15573-38-3
Product Catalog
15-8021
Phosphorus › Tris(trimethylsilyl)phosphine, min. 98% (10 wt% in hexane)| CAS Number: | 15573-38-3 |
| MDL Number: | MFCD00015487 |
| Molecular Formula: | C9H27PSi3 |
| Molecular Weight: | 250.54 |
| Chemical Formula: | [(CH3)3Si]3P |
| Color and Form: | colorless liq. |
| Note: |
Stability: air sensitive
Safety: Hazardous
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Tris(trimethylsilyl)phosphine, min. 98% (10 wt% in hexane) |
| Product Number: | 15-8021 |
| CAS Registry Number: | 15573-38-3 |
| Formula: | [(CH3)Si]3P |
| EINECS Number: | none |
| Chemical Family: | organophosphine compound |
| Synonym: | Tris(trimethylsilyl)phosphane |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 15573-38-3 | 10 | no data | no data |
| hexane | 110-54-3 | 90 | 50ppm | 1800mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Extremely flammable liquid with a pungent odor. Irritating to skin, eyes and respiratory tract. Harmful by inhalation, in contact with skin and if swallowed. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes. |
| Eye Contact: | Cause irrtiation to the eyes with redness and a burning sensation. |
| Skin Contact: | irritating to skin. Harmful in contact with skin. May be absorbed through the skin. |
| Inhalation: | Harmful through inhalation. Irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and headache. |
| Acute Health Effects: | Irritating to skin, eyes and respiratory tract. Harmful through inhalation, in contact with skin and if swallowed. Possible risk of harm to the unborn child. |
| Chronic Health Effects: | Possible risk of impaired fertility. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | -7°F |
| Autoignition Temperature: | pyrophoric residue |
| Explosion Limits: | LEL (1.7%) UEL (7.7%) |
| Extinguishing Medium: | carbon dioxide, dry powder or foam. |
| Special Fire Fighting Procedures: | Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | Burning material may emit toxic and corrosive fumes. |
| Unusual Fire or Explosion Hazards: | Highly flammable. Formation of explosive air/vapor mixtures is possible. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | 'Residue may ignite spontaneously in air. Avoid static discharge. Burning material may release toxic fumes. In case of poor ventilation, leave the area unless fitted with a self-contained breathing apparatus. Small spills can be mixed with ground limestone, sodium bicarbonate, or other suitable absorbents, swept up, and held in a closed metal can. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat. Material should be transferred under an inert atmosphere of nitrogen or argon in an efficient fume hood. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothes and gloves. |
| Ventilation: | It is imperative that this material be handled in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liquid |
| Molecular Weight: | 250.54 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | pungent and noxious odor |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air-sensitive liquid |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with oxidizing agents, prolonged contact with air and ignition sources. |
| Incompatibility: | oxidizing agents and halogens |
| Decomposition Products: | carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available on title compound. For hexane--Standard Draize Test (rabbit); 10mg(mild). Inhalation (human); TCLo: 190ppm/8W. Oral (rat); LD50: 28710mg/kg. Inhalation (rat); LC50: 48000ppm/4H. Intraperitoneal (rat); LDLo: 9100mg/kg. Intravenous (mouse); LDLo: 831mg/kg. Inhalation (rat); TCLo: 2000ppm/12H/24W-I. Acts as a general anesthetic, respiratory depression, altered sleep time, effects on nerves, decreased weight gain, muscle weakness, and changes to the liver and blood. Toxic effects observed in the embryo and fetus of test animals. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | For hexane: Possible mutagen |
| Tetratogenic Effects: | For hexane: Possible reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Avoid release to the environment. Dispose of acording to federal, state and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable Liquids, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 1993 |
| Shipping Name (IATA): | Flammable Liquid, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | I |
| UN ID Number (IATA): | UN# 1993 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | Listed in the TSCA inventory, Regulated by SARA 313. |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 1/23/2004 |
| Revision Date: | 12/14/2011 |
