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CAS Number: 40244-90-4
Product Catalog

15-1800
Phosphorus Di-i-propylchlorophosphine, min. 98%
CAS Number: 40244-90-4
MDL Number: MFCD00015027
Molecular Formula: C6H14ClP
Molecular Weight: 152.60
Chemical Formula: (C3H7)2PCl
Color and Form: colorless liq.
Note:  

Stability: air sensitive, moisture sensitive

Safety: Hazardous

Physical Characteristics: density 0.959, flash point 39°F

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SECTION 1: Product Identification
Chemical Name: Di-i-propylchlorophosphine, min. 98%
Product Number: 15-1800
CAS Registry Number: 40244-90-4
Formula: (C3H7)2PCl
EINECS Number: none
Chemical Family: organophosphine halide
Synonym: Chlorodiisopropylphosphine
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 40244-90-4 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Material has a pungent odor. Inhalation of vapors may lead to headache, dizziness and irritation of mucous membranes. May be corrosive to skin and eyes. Harmful by inhalation and in contact with skin.
Primary Routes of Exposure: Ingestion, inhalation, eyes, skin
Eye Contact: Causes burns to the eyes.
Skin Contact: Causes burns to the skin. Harmful in contact with skin.
Inhalation: The material has a pungent odor. Harmful by inhalation. Inhalation may lead to headaches and dizziness. Corrosive to the nose and mucous
Ingestion: Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset.
Acute Health Effects: Vapor is corrosive to eyes, skin, mucous membranes, and gastrointestinal and respiratory tract, with the primary health effects being burns, blindness, ulceration, and pulmonary edema.
Chronic Health Effects: No information on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam.
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazard.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Eliminate all ignition sources. Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Poorly ventilated workspaces will require evacuation. Emergency response teams will require self-contained breathing apparatus.
SECTION 7: Handling and Storage
Handling and Storage: Material must be handled and stored under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless liquid
Molecular Weight: 152.6
Melting Point: no data
Boiling Point: 46-47°C (10 Torr)
Vapor Pressure: no data
Specific Gravity: no data
Odor: sharp, acidic odor
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: air and moisture sensitive liquid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: water, oxidizing agents, halogens and active metals.
Decomposition Products: carbon dioxide, carbon monoxide, hydrogen chloride, organic vapors, chlorinated hydrocarbons and phosphorus pentoxide.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Flammable liquids, Corrosive, N.O.S.
Hazard Class (CFR): 3
Additional Hazard Class (CFR): 8
Packaging Group (CFR): II
UN ID Number (CFR): UN# 2924
Shipping Name (IATA): Flammable liquid, Corrosive, N.O.S.
Hazard Class (IATA): 3
Additional Hazard Class (IATA): 8
Packaging Group (IATA): II
UN ID Number (IATA): UN# 2924
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 1/23/2004
Revision Date: 7/29/2011

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