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CAS Number: 148432-44-4
Product Catalog

15-1461
Phosphorus › Di-2-norbornylphosphine, min. 98% (mixture of endo and exo isomers) (10 wt% in hexane)
CAS Number: 148432-44-4
MDL Number: MFCD04117684
Molecular Formula: C14H23P
Molecular Weight: 222.31
Chemical Formula: (C7H11)2PH
Color and Form: colorless liq.
Note:  

Stability: air sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Di-2-norbornylphosphine, min. 98% (mixture of endo and exo isomers) (10 wt% in hexane)
Product Number: 15-1461
CAS Registry Number: 148432-44-4
Formula: (C7H11)2PH
EINECS Number: none
Chemical Family: organophosphine ligand
Synonym: Bis-2-norbornylphosphane, in hexane
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 148432-44-4 10 no data no data
hexane 110-54-3 90 50ppm 1800mg/m3
SECTION 3: Hazards Identification
Emergency Overview: Flammable liquid. Irritating to skin, eyes and respiratory tract. Inhalation may depress central nervous system causing dizziness, headache and nausea.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes.
Eye Contact: Contact causes irritation and redness. May cause a burning sensation.
Skin Contact: Contact with skin results in local irritation. May be absorbed through the skin.
Inhalation: Inhalation of vapors may depress the central nervous system causing dizziness and difficulty in walking. Irritating to the lungs.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and headache.
Acute Health Effects: Irritating to skin, eyes and respiratory tract. Inhalation may lead to dizziness and difficulty walking. Possible risk of harm
Chronic Health Effects: Possible risk of impaired fertility. May cause lung damage if swallowed.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: -7°F
Autoignition Temperature: no data
Explosion Limits: LEL (1.7%) UEL (7.7%)
Extinguishing Medium: carbon dioxide, dry powder or foam.
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Unusual Fire or Explosion Hazards: Extremely flammable.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: 'Residue may ignite spontaneously in air. Avoid static discharge. Burning material may release toxic fumes. In case of poor ventilation, leave the area unless fitted with a self-contained breathing apparatus. Small spills can be mixed with ground limestone, sodium bicarbonate, or other suitable absorbents, swept up, and held in a closed metal can.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat. Material should be transferred under an inert atmosphere of nitrogen or argon in an efficient fume hood.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: It is imperative that this material be handled in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: colorless liquid
Molecular Weight: 222.31
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: pungent and noxious odor
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air-sensitive liquid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with oxidizing agents, prolonged contact with air and ignition sources.
Incompatibility: oxidizing agents and halogens
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.
SECTION 11: Toxicological Information
RTECS Data: No information available on title compound. For hexane--Standard Draize Test (rabbit); 10mg(mild). Inhalation (human); TCLo: 190ppm/8W. Oral (rat); LD50: 28710mg/kg. Inhalation (rat); LC50: 48000ppm/4H. Intraperitoneal (rat); LDLo: 9100mg/kg. Intravenous (mouse); LDLo: 831mg/kg. Inhalation (rat); TCLo: 2000ppm/12H/24W-I. Acts as a general anesthetic, respiratory depression, altered sleep time, effects on nerves, decreased weight gain, muscle weakness, and changes to the liver and blood. Toxic effects observed in the embryo and fetus of test animals.
Carcinogenic Effects: For hexane: Insufficient data
Mutagenic Effects: For hexane: Possible mutagen
Tetratogenic Effects: For hexane: Possible reproductive effector
SECTION 12: Ecological Information
Ecological Information: For hexane: Avoid relese to the environment. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Flammable Liquids, N.O.S.
Hazard Class (CFR): 3
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1993
Shipping Name (IATA): Flammable Liquid, N.O.S.
Hazard Class (IATA): 3
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1993
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not reportable.
Second Ingredient: Listed in the TSCA inventory, reportable under SARA 313.
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 1/23/2004
Revision Date: 9/27/2011

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