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CAS Number: 65090-77-9
Product Catalog

11-1200
Sodium Sodium-i-propylcyclopentadienide
CAS Number: 65090-77-9
MDL Number: MFCD00145308
Molecular Formula: C8H11Na
Molecular Weight: 130.17
Chemical Formula: (C3H7)C5H4Na
Color and Form: white to off-white xtl.
Note:  

Stability: air sensitive, moisture sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Sodium-i-propylcyclopentadienide
Product Number: 11-1200
CAS Registry Number: 65090-77-9
Formula: (C3H7)C5H4Na
EINECS Number: none
Chemical Family: metallocene
Synonym: Sodium isopropylcyclopentadienide
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 65090-77-9 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and mucous membranes. May be harmful through ingestion, inhalation and skin absorption.
Primary Routes of Exposure: Ingestion, inhalation, skin
Eye Contact: Causes mild to moderate irritation of the eyes.
Skin Contact: Causes mild to moderate irritation of the skin. May be harmful through skin absorption.
Inhalation: Causes irritation to the nose, mucous membranes and respiratory tract. May be harmful if inhaled.
Ingestion: No information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Effects: Causes irritation to skin, eyes and respiratory tract. May be harmful through inhalation, ingestion and skin absorption.
Chronic Health Effects: No information on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire, this material may emit toxic and corrosive fumes.
Unusual Fire or Explosion Hazards: 'Flammable solid. Dust may form explosive mixtures with air.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Use no water. Eliminate sources of ignition. Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up. Wastes may continue to emit toxic phosphine gas.
SECTION 7: Handling and Storage
Handling and Storage: Handle and store the material under a dry, inert atmosphere of nitrogen or argon. Keep away from heat.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white to off-white xtl.
Molecular Weight: 130.17
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: not determined
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: air and moisture sensitive
Hazardous Polymerization: No hazardous polymerization
Conditions to Avoid: contact with moisture and mineral acids
Incompatibility: water, alcohols, oxidizers, halogens, and mineral acids.
Decomposition Products: carbon monoxide, carbon dioxide, sodium hydroxide, and organic fumes.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Flammable solids, inorganic, N.O.S.
Hazard Class (CFR): 4.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 3178
Shipping Name (IATA): Flammable solid, inorganic, N.O.S.
Hazard Class (IATA): 4.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 3178
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 6/17/2004
Revision Date: 12/21/2011

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