| CAS Number: | 109-63-7 |
| MDL Number: | MFCD00013194 |
| Molecular Formula: | BF3 |
| Molecular Weight: | 141.94 |
| Chemical Formula: | BF3·O(C2H5)2 |
| Color and Form: | pale yellow liq. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: boiling point 126°C, flash point 118°F, density 1.125 (25°C)
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Boron fluoride, ethyl ether complex (47-48% Boron fluoride) |
| Product Number: | 93-0519 |
| CAS Registry Number: | 109-63-7 |
| Formula: | BF3.O(C2H5)2 |
| EINECS Number: | 203-689-8 |
| Chemical Family: | metal halide |
| Synonym: | Boron trifluoride, ethylether complex |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 109-63-7 | 100 | 2.5mg/m3 (as F) | 2.5mg/m3 (as F) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Flammable liquid and vapor. Inhalation may cause dizziness and headache. Corrosive to eyes, skin and mucous membranes. Ingestion may cause nausea and vomiting. |
| Primary Routes of Exposure: | Eye, skin and inhalation |
| Eye Contact: | Causes burns to the eyes. |
| Skin Contact: | Causes caustic burns to the skin. Prolonged contact may dry the skin and lead to rashes or more severe irritation. |
| Inhalation: | Corrosive to the nose, mucous membranes and respiratory tract. Can cause dizziness, headaches, nausea and impaired coordination. |
| Ingestion: | Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset. |
| Acute Health Effects: | Corrosive to skin, eyes and mucous membranes. More severe effects (ingestion and inhalation) are dizziness, nausea, vomiting. |
| Chronic Health Effects: | Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 118°F |
| Autoignition Temperature: | not determined |
| Explosion Limits: | not determined |
| Extinguishing Medium: | dry chemical, carbon dioxide, water spray or foam. |
| Special Fire Fighting Procedures: | If this material is involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | carbon dioxide, carbon monoxide, soot, boron oxide particulate. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be absorbed into vermiculite or other suitable adsorbent. Larger spills must be contained in order to avoid contamination of the soil, sewers systems or bodies of water. Eliminate all potential ignition sources. Absorb the material into clay, sawdust or other suitable adsorbent. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. This product will react with atmospheric moisture and chemically degrade. Transfer material under an inert atmosphere of nitrogen or argon |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Work with this product in a well-ventilated area, preferably a fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134 |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | liq. |
| Molecular Weight: | 141.94 |
| Melting Point: | no data |
| Boiling Point: | 126°C |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.125 (25°) |
| Odor: | none |
| Solubility in Water: | Reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with ignition source |
| Incompatibility: | Oxidizing agents, active metals, water and alcohols |
| Decomposition Products: | carbon dioxide, carbon monoxide, hydrogen fluoride, fluoriinated hydrocarbons, organic fumes, and a boron oxide mist. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No specific information available from the RTECS files. Boron compounds generally affect the central nervous system. Poisoning can cause depression of the circulation, vomiting and diarrhea followed by shock and coma |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of in accordance with local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Boron trifluoride diethyl etherate |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | 3 |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 2604 |
| Shipping Name (IATA): | Boron trifluoride diethyl etherate |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | 3 |
| Packaging Group (IATA): | I |
| UN ID Number (IATA): | UN# 2604 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | listed in the TSCA inventory. |
| SARA (Title 313): | not reportable under SARA Title (313). |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 11/28/1999 |
| Revision Date: | 2/23/2012 |