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CAS Number: 7440-02-0
28-1900
Nickel › Nickel, 64% powder on silica, reduced and stabilized (Ni-5249P)| CAS Number: | 7440-02-0 |
| MDL Number: | MFCD06798735 |
| Molecular Formula: | |
| Molecular Weight: | |
| Chemical Formula: | |
| Color and Form: | black pwdr. (d50=5 μm) |
| Note: | Sold in collaboration with BASF for research purposes only. |
Safety: Hazardous
Physical Characteristics: surface area 55m2/g
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Nickel, 64% powder on silica, reduced and stabilized (Ni-5249P) |
| Product Number: | 28-1900 |
| CAS Registry Number: | 7440-02-0 |
| Formula: | Ni on silica |
| EINECS Number: | 231-111-4 |
| Chemical Family: | supported metal catalyst |
| Synonym: | none |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 7440-02-0 | 64 | 1.5mg/m3 (as Ni) | 1mg/m3 (as Ni insoluble) |
| Silica | 1343-98-2 | 36 | 10mg/m3 (amorphous) | 15mg/m3 (dust) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | May cause sensitization by skin contact. Possible harm to the unborn child and possible risk of irreversible effects. May cause cancer. |
| Primary Routes of Exposure: | Contact with skin and eyes. Dust inhalation. |
| Eye Contact: | May cause slight to mild irritation of the eyes. |
| Skin Contact: | May cause slight to moderate irritation of the skin. May cause sensitization by skin contact. |
| Inhalation: | Dust or fumes may be irritating to the nose, mucous membranes and respiratory tract. Individuals hypersensitive to nickel may develop wheezing. |
| Ingestion: | Harmful if swallowed. Ingestion of large amounts may cause gastrointestinal irritation, nausea, vomiting and headache. |
| Acute Health Effects: | May cause sensitization by skin contact. May be irritating to skin, eyes and respiratory tract. |
| Chronic Health Effects: | Possible harm to the unborn child and possible risk of irreversible effects. May cause cancer. (Animal studies with nickel powder surgically instilled or implanted for long periods in lungs, trachea, under skin, - see NTP and IARC discussions) |
| NTP: | Yes |
| IARC: | Yes |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | dry powder or water |
| Special Fire Fighting Procedures: | No special firefighting procedures required for this product. |
| Hazardous Combustion and Decomposion Products: | none |
| Unusual Fire or Explosion Hazards: | Marginally flammable solid. Dust may form explosive mixtures with air. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite, ground limestone or soda ash and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | black powder(d50=5 microns) |
| Molecular Weight: | not applicable |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | none |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture stable |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Mixtures of fine dust with air, contact with ignition sources. |
| Incompatibility: | Mineral acids, halogens, acetylene, hydrazinium nitrate and oxidizing agents, sulfur. |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Oral (rat); LDLo: 5g/kg. Intraperitoneal (rat); LD50: 250mg/kg. Intratracheal (rat); LDLo: 12mg/kg. Intravenous (mouse); LDLo: 50mg/kg. Subcutaneous (cat); LDLo: 12500ug/kg. Intraperitoneal (rabbit); LDLo: 7mg/kg. Inhalation (rat); TCLo: 100ug/m3/24H/17W-I. Oral (mouse); TDLo: 500mg/kg/5D-I. Subcutaneous (rat); TDLo: 2000mg/kg/6W-I. Intraperitoneal (rat); TDLo: 100mg/kg/21W-I. Hampster kidney; morphological transformation: 400mg/L. |
| Carcinogenic Effects: | Tumorigen |
| Mutagenic Effects: | Mutagen |
| Tetratogenic Effects: | Reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Metal catalyst, Dry |
| Hazard Class (CFR): | 4.2 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 2881 |
| Shipping Name (IATA): | Metal catalyst, Dry |
| Hazard Class (IATA): | 4.2 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 2881 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory |
| SARA (Title 313): | Reportable under SARA Title 313. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/12/2004 |
| Revision Date: | 12/13/2011 |
