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CAS Number: 12145-60-7
Product Catalog

28-0900
Nickel › Methallylnickel chloride dimer
CAS Number: 12145-60-7
MDL Number: MFCD04038737
Molecular Formula: C8H14Cl2Ni2
Molecular Weight: 298.49
Chemical Formula: [C4H7NiCl]2
Color and Form: orange-brown xtl.
Note:  

Stability: air sensitive, moisture sensitive, store cold

28-0900

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SECTION 1: Product Identification
Chemical Name: Methallylnickel chloride dimer
Product Number: 28-0900
CAS Registry Number: 12145-60-7
Formula: [C4H7NiCl]2
EINECS Number: none
Chemical Family: organometallic complexes
Synonym: Chloro(methallyl)nickel (II) dimer
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 12145-60-7 100 0.2mg/m3(as Ni) 1mg/m3 (as Ni)
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. Dust may cause headaches, sore throat, shortness of breath and lung damage. Ingestion of large amounts may cause convulsions and asphyxia. May cause cancer.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Causes mild to moderate irritation to the eyes. May cause redness and pain.
Skin Contact: Causes moderate irritation of the skin with redness or rash. Prolonged contact may cause dermatitis.
Inhalation: Inhalation causes irritation to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness and convulsions.
Acute Health Effects: Irritating to skin, eyes and respiratory tract. May causes intestinal disorders, convulsions, asphyxia, sensitization dermatitis, allergic asthma and pneumonitis. May cause cancer.
Chronic Health Effects: Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause cancer.
NTP: Yes
IARC: Yes
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam.
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Keep material in a tightly sealed container. Store cold. Prolonged exposure to moisture will result in degradation of the product. Handle and store under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: orange-brown xtl.
Molecular Weight: 298.49
Melting Point: none
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive (store cold)
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: moisture sensitive (store cold)
Incompatibility: oxygen, oxidizing agents and halogens
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes, hydrochloric acid and chloride.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: Carcinogen (as Ni)
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): See category code N495 for reporting.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 1/23/2004
Revision Date: 8/15/2011

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