| CAS Number: | 13007-92-6 |
| MDL Number: | MFCD00010945 |
| Molecular Formula: | C6CrO6 |
| Molecular Weight: | 220.06 |
| Chemical Formula: | Cr(CO)6 |
| Color and Form: | white xtl. |
| Note: |
Safety: Hazardous
Physical Characteristics: melting point 154-155°C, density 1.77
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Chromium carbonyl, 99% |
| Product Number: | 24-0180 |
| CAS Registry Number: | 13007-92-6 |
| Formula: | Cr(CO)6 |
| EINECS Number: | 235-852-4 |
| Chemical Family: | metal carbonyl complexes |
| Synonym: | Chromium hexacarbonyl, hexacarbonylchromium (0) |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 13007-92-6 | 100 | 0.05 mg/m3 | 0.5 mg/m3 (as Cr) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Harmful if swallowed. Toxic by inhalation. Inhalation can lead to headaches and dizziness. Prolonged exposure can lead to convulsions and coma. |
| Primary Routes of Exposure: | Ingestion, inhalation |
| Eye Contact: | May cause mild irritation to the eyes. |
| Skin Contact: | May cause mild irritation to the skin. |
| Inhalation: | Toxic by inhalation. Inhalation could lead to dizziness and headache. |
| Ingestion: | Harmful if swallowed. |
| Acute Health Effects: | Harmful if swallowed. Toxic by inhalation. Inhalation can lead to headaches and dizziness. Prolonged exposure can lead to convulsions and coma. |
| Chronic Health Effects: | No information on long term exposure. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | none |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, dry chemical or foam |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH-approved positive pressure self-contained breathing apparatus. |
| Hazardous Combustion and Decomposion Products: | carbon monoxide, carbon dioxide, and chromium oxide dust. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small quantities can be mixed with sodium carbonate or vermiculite and swept up. If large quantities are spilled, and ventilation is not available, personnel should be fitted with a self- contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a cool, dry, well-ventilated area away from heat and direct sunlight. Keep containers tightly sealed. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling chemical substances. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | This product should be handled in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white crystals |
| Molecular Weight: | 220.06 |
| Melting Point: | 154-155°C |
| Boiling Point: | decomposes |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.77 |
| Odor: | musty odor |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture-stable solid |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with strong oxidizing agents. |
| Incompatibility: | Strong oxidizing agents, halogens. |
| Decomposition Products: | carbon monoxide, carbon dioxide, chromium oxide dust and fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Oral (rat); LD50; 230mg/kg. Inhalation (rat); LCLo: 35mg/m3/30M. Oral (mouse); LD50: 150mg/kg. Intravenous (mouse); LD50: 30mg/kg. Inhalation (rat); TCLo: 1600ng/m3/4H/17-W-I. Implant (rat); TDLo: 75mg/kg. Cytogenetic analysis (rodent); 2 gm/L. Based on animal studies, effects of inhalation include convulsions, tetany, and dyspnea, changes in lung weight, liver weight and bladder weight. |
| Carcinogenic Effects: | Chromium is a confirmed human carcinogen. |
| Mutagenic Effects: | Equivocal tumorigenic agent by RTECS criteria. |
| Tetratogenic Effects: | No information available. |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of this material according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Metal carbonyls, Solid, N.O.S. |
| Hazard Class (CFR): | 6.1 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 3466 |
| Shipping Name (IATA): | Metal carbonyls, Solid, N.O.S. |
| Hazard Class (IATA): | 6.1 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 3466 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | listed on the TSCA inventory |
| SARA (Title 313): | Title compound: See Category Code N090 for Reporting |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/23/1999 |
| Revision Date: | 5/02/2006 |