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CAS Number: 7440-67-7

93-4047
Zirconium Zirconium powder (99.5%)
CAS Number: 7440-67-7
MDL Number: MFCD00011303
Molecular Formula: Zr
Molecular Weight: 91.22
Chemical Formula: Zr
Color and Form: -50 mesh pwdr.
Note:  

Safety: Hazardous

Physical Characteristics: melting point 1852°C, boiling point 3577°C, density 6.506

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SECTION 1: Product Identification
Chemical Name: Zirconium powder (99.5%)
Product Number: 93-4047
CAS Registry Number: 7440-67-7
Formula: Zr (In water)
EINECS Number: 231-176-9
Chemical Family: metal or element
Synonym: None
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 7440-67-7 100 5mg/m3 (as Zr) no data
water 7732-18-5 50 no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. Inhalation hazard if dehydrated to a fine dust or fume.
Primary Routes of Exposure: Ingestion, inhalation (of dust or fume)
Eye Contact: The dust (after dehydration or water slurry) causes mild to moderate irritation of the eyes.
Skin Contact: The powder causes mild to moderate irritation of the skin.
Inhalation: Hazard associated with inhalation of dried fine dust or fume. Irritating to nasal cavity and respiratory tract.
Ingestion: Ingestion can cause irritation of the mouth, throat, and esophagus
Acute Health Effects: Irritating to skin, eyes and respiratory tract. Ingestion can lead to gastrointestinal effects, vomiting and nausea.
Chronic Health Effects: Long term skin or inhalation exposure to powder may lead to an allergic reaction in some susceptible individuals.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: 68°F as dust
Explosion Limits: unknown
Extinguishing Medium: Class D metal fire agent, dry salt or sand.
Special Fire Fighting Procedures: Burning metal produces zirconium dioxide fumes. Fire fighters should be equipped with a self-contained breathing apparatus.
Hazardous Combustion and Decomposion Products: Zirconium oxide as an oxidation product.
Unusual Fire or Explosion Hazards: Material may spontaneously ignite on exposure to air, especially in the form of a dry fine dust.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: In the case of a spill, the fine powder should be covered with sodium carbonate or dolomite in order to reduce the formation of dust. Sweep up the mixture.
SECTION 7: Handling and Storage
Handling and Storage: Store and handle the material under an inert atmosphere of nitrogen or argon.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: If in the form of a dry fine dust, handle the material in an efficient fume hood.
Respirator: If handling material in the form of a dry fine dust and ventilation is not available, a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: -50 mesh pwdr.
Molecular Weight: 91.22
Melting Point: 1852
Boiling Point: 3577
Vapor Pressure: no data
Specific Gravity: 6.506
Odor: none
Solubility in Water: insoluble
SECTION 10: Stability and Reactivity
Stability: air sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Contact of dried powder with air may result in auto ignition.
Incompatibility: air, oxidizing agents, copper oxide, halogens, halocarbons, strong bases.
Decomposition Products: none
SECTION 11: Toxicological Information
RTECS Data: No specific information available on this product.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Zirconium powder, dry
Hazard Class (CFR): 4.2
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 2008
Shipping Name (IATA): Zirconium powder, dry
Hazard Class (IATA): 4.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 2008
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory
SARA (Title 313): Title compound not listed
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 1/05/2001
Revision Date: 8/05/2011

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