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CAS Number: 15461-27-5

93-4036
Zirconium Zirconium(IV) dichloride oxide hydrate (99.9%-Zr)
CAS Number: 15461-27-5
MDL Number: MFCD00149897
Molecular Formula: Cl2OZr
Molecular Weight: 178.13
Chemical Formula: ZrOCl2·XH2O
Color and Form: white pwdr.
Note:  

Safety: Hazardous

Physical Characteristics: density 1.910

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SECTION 1: Product Identification
Chemical Name: Zirconium (IV) dichloride oxide hydrate (99.9%-Zr)
Product Number: 93-4036
CAS Registry Number: 15461-27-5
Formula: ZrOCl2.XH2O
EINECS Number: 231-717-9
Chemical Family: metal oxyhalide
Synonym: Zirconium oxychloride hydrate
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 15461-27-5 100 5mg/m3 (as Zr) 5mg/m3 (as Zr)
SECTION 3: Hazards Identification
Emergency Overview: Corrosive to skin and eyes. Material hydrolyzes in contact with moisture releasing toxic and corrosive fumes of hydrogen chloride and aqueous hydrochloric acid.
Primary Routes of Exposure: Contact with skin and eyes. Inhalation of dust.
Eye Contact: Corrosive to the eyes.
Skin Contact: Causes burns to the skin.
Inhalation: Forms hydrogen chloride in the presence of moisture. Inhalation can lead to chemical burns of the respiratory tract.
Ingestion: No information is available on the acute physiological effects of ingestion.
Acute Health Effects: Corrosive to skin, eyes and respiratory tract and cause eye, skin burns, dyspnea (breathing difficulty), and pulmonary edema
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: None. Material is non-flammable.
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: none
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable inert material and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store solid in a tightly sealed container.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: The solid may form corrosive vapors. It should be handled in an efficient fume hood.
Respirator: If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white pwdr.
Molecular Weight: 178.13
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: 1.91
Odor: pungent odor
Solubility in Water: soluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: none
Decomposition Products: water, metal oxychloride, metal oxide
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive Solids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): III
UN ID Number (CFR): UN# 1759
Shipping Name (IATA): Corrosive Solid, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): III
UN ID Number (IATA): UN# 1759
SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 6/11/2001
Revision Date: 7/29/2011

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