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CAS Number: 7446-31-3

40-4750
Zirconium Zirconium(IV) sulfate tetrahydrate (99.99+%-Zr) PURATREM
CAS Number: 7446-31-3
MDL Number: MFCD00149267
Molecular Formula: O8S2Zr
Molecular Weight: 283.33 (355.39)
Chemical Formula: Zr(SO4)2·4H2O
Color and Form: white xtl.
Note:  

Physical Characteristics: melting point 100°C (-3H2O)

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SECTION 1: Product Identification
Chemical Name: Zirconium (IV) sulfate tetrahydrate (99.99+%-Zr) PURATREM
Product Number: 40-4750
CAS Registry Number: 14644-61-2
Formula: Zr(SO4)2.4H2O
EINECS Number: 238-694-4
Chemical Family: metal sulfate
Synonym: Sulfuric acid, zirconium(4+) salt (2:1), Zirconium sulfate
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 14644-61-2 100 5mg/m3 (as Zr) 5mg/m3 (as Zr)
SECTION 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract. This material partially hydrolyzes in water to form dilute sulfuric acid, a strong irritant.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Dust is a moderate to severe irritant to the eyes.
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Inhalation: Inhalation of dust may irritate the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion: Ingestion may lead to nausea, vomiting and diarrhea.
Acute Health Effects: Acidic behavior causes irritation of skin, eyes and respiratory and gastrointestinal tracts.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic fumes of sulfur oxides.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed bottle away from moisture.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: If possible, handle the material in an efficient fume hood.
Respirator: In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 283.33 (355.39)
Melting Point: 100°C (-3H2O)
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: none
Solubility in Water: soluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: Strong bases
Decomposition Products: In water, dilute sulfuric acid
SECTION 11: Toxicological Information
RTECS Data: Oral (rat); LD50: 3500 mg/kg. Intraperitoneal (rat); LD50: 175 mg/kg. Subcutaneous (rat); LDLo: 500 mg/kg. Intratesticular (rat); TDLo: 22667 ug/kg. Mouse Lymphocyte; Unscheduled DNA synthesis: 20 umol/L.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 10/08/2001
Revision Date: 12/13/2011

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