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CAS Number: 10170-68-0

24-0280
Chromium Chromium(III) chloride tetrahydrofuran adduct, 98%
CAS Number: 10170-68-0
MDL Number: MFCD00013222
Molecular Formula: C12H24Cl3CrO3
Molecular Weight: 374.67
Chemical Formula: CrCl3(C4H8O)3
Color and Form: purple pwdr.
Note:  

Stability: moisture sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Chromium(III) chloride tetrahydrofuran adduct, 98%
Product Number: 24-0280
CAS Registry Number: 10170-68-0
Formula: C12H24Cl3CrO3
EINECS Number: none
Chemical Family: metal halide
Synonym: Chromium trichloride tetrahydrofuran adduct
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title compound 10170-68-0 100 0.5mg/m3 (as Cr) 0.5mg/m3 (as Cr)
SECTION 3: Hazards Identification
Emergency Overview: Harmful if swallowed. Corrosive to skin, eyes and respiratory tract. Possible risk of harm to the unborn child, impaired fertility and irreversible effects. Tetrahydrofuran can cause drowsiness.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Dust and vapors cause burns to the eyes and blindness.
Skin Contact: Causes burns to the skin. May cause sensitization through skin contact.
Inhalation: Corrosive to the nose, mucous membranes and respiratory tract. May cause sensitization through inhalation.
Ingestion: Harmful if swallowed. Ingestion may cause damage to the mouth, throat and esophagus.
Acute Health Effects: Corrosive to skin, eyes and respiratory tract. Possible risk of harm to the unborn child.
Chronic Health Effects: Although less toxic than Chromium (VI), chromium (III) chloride may act as a mutagen and reproductive effector. Possible risk of impaired fertility and irreversible effects. In animal studies, tetrahydrofuran acted as a tumorigen (liver), mutagen and reproductive effector.
NTP: Yes
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide, dry powder or foam
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic and corrosive fumes.
Unusual Fire or Explosion Hazards: No unususal fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with sodium bicarbonate, lime or calcium carbonate and swept up. Avoid raising dust.
SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed container away from moisture. Handle in a fume hood under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: purple powder
Molecular Weight: 374.67
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: ethereal odor
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: water, alcohols, oxidizing agents, oxygen and active metals
Decomposition Products: Chromium oxychloride, hydrogen chloride, carbon dioxide, carbon monoxide, organic fumes.
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data
Mutagenic Effects: No data
Tetratogenic Effects: No data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive solid, Acidic, Inorganic, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): III
UN ID Number (CFR): UN# 3260
Shipping Name (IATA): Corrosive solid, Acidic, Inorganic, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): III
UN ID Number (IATA): UN# 3260
SECTION 15: Regulatory Information
TSCA: Chromium(III) chloride: Listed in the TSCA inventory
SARA (Title 313): Title compound: See category code N090 for reporting
Second Ingredient: no data
Third Ingredient: no data
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 12/11/2009
Revision Date: 12/27/2011

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