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CAS Number: 546-68-9
Product Catalog
98-4030
Titanium › Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok® cylinder (96-1070) for CVD/ALD| CAS Number: | 546-68-9 |
| MDL Number: | MFCD00008871 |
| Molecular Formula: | |
| Molecular Weight: | 284.25 |
| Chemical Formula: | Ti[OCH(CH3)2]4 |
| Color and Form: | colorless liq. |
| Note: | High temperature Swagelok® cylinder assembly 96-1071 available at extra cost. |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: melting point 20°C, boiling point 58°C/1mm, flash point 81°F, density 0.9550
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok® cylinder (96-1070) for CVD/ALD |
| Product Number: | 98-4030 |
| CAS Registry Number: | 546-68-9 |
| Formula: | Ti[OCH(CH3)2]4 |
| EINECS Number: | 208-909-6 |
| Chemical Family: | metal alkoxide |
| Synonym: | Isopropyl orthotitanate, Titanium isopropylate, Titanium tetraisopropoxide, tetraisopropoxytitanium |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title compound | 546-68-9 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | The liquid irritates the skin, eyes and respiratory tract. Moisture will produce isopropanol vapor which may cause drowsiness. |
| Primary Routes of Exposure: | Inhalation, ingestion, contact with skin and eyes. |
| Eye Contact: | The liquid and the isopropanol released on hydrolysis causes irritation of the eyes. |
| Skin Contact: | Dehydrating agent. Liquid causes irritation of the skin. |
| Inhalation: | Liquid causes irritation to the upper respiratory tract. Isopropanol vapor may cause dizziness and drowsiness. |
| Ingestion: | Ingestion may cause moderate irritation of the gastrointestinal tract, nausea, vomiting, headache and coma. |
| Acute Health Effects: | The product is a mild irritant. Isopropanol is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time. |
| Chronic Health Effects: | No data is available for this product. Isopropanol is a possible mutagen, tumorigen and reproductive effector. Prolonged exposure may damage nerves, kidneys and the cardiovascular system. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 81?F |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, foam or dry powder |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire, this material may emit toxic organic fumes and titania dust. |
| Unusual Fire or Explosion Hazards: | Flammable liquid. No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all ignition sources. Avoid contact with water. Small spills may be absorbed into diatomaceous earth, sand or other suitable adsorbent and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container in a cool, dry place. If container is left open, product may absorb moisture from the atmosphere and release isopropanol vapor. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liq. |
| Molecular Weight: | 284.25 |
| Melting Point: | no data |
| Boiling Point: | 58?/1mm |
| Vapor Pressure: | no data |
| Specific Gravity: | 0.955 |
| Odor: | alcohol-like odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive liq. |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Keep away from heat and ignition sources including open flame and electrostatic discharge. |
| Incompatibility: | Oxidizing agents |
| Decomposition Products: | carbon monoxide, carbon dioxide, organic vapors, metal oxides and carbonates. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Administration onto the skin (rbt); Standard Draize test: 500 mg/24H. Administration into the eye (rbt); Standard Draize test: 20 mg/24H. Oral (rat); LD50: 7460 uL/kg. Administration onto the skin (rbt); LD50: >16 mL/kg. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | no data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of this material according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable liquids, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | III |
| UN ID Number (CFR): | UN# 1993 |
| Shipping Name (IATA): | Flammable liquid, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | III |
| UN ID Number (IATA): | UN# 1993 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory |
| SARA (Title 313): | Title compound not listed |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 4/21/2011 |
| Revision Date: | 4/21/2011 |
