| CAS Number: | 19529-53-4 |
| MDL Number: | MFCD00058726 |
| Molecular Formula: | F12P4Pt |
| Molecular Weight: | 547.01 |
| Chemical Formula: | Pt(PF3)4 |
| Color and Form: | colorless to light yellow liq. |
| Note: |
Stability: air sensitive, moisture sensitive, store cold
Safety: Hazardous
Physical Characteristics: boiling point ~80°C, density 2.2, vapor pressure 240mm (55°C)
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Tetrakis(trifluorophosphine)platinum(O) (ampouled under PF3) |
| Product Number: | 98-0925 |
| CAS Registry Number: | 19529-53-4 |
| Formula: | Pt(PF3)4 |
| EINECS Number: | 243-137-3 |
| Chemical Family: | metal-phosphine complexes |
| Synonym: | Trifluorophosphine platinum complex |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 19529-53-4 | 100 | 2.5mg/m3 (as F) | 2.5mg/m3 (as F) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Corrosive to skin, eyes and respiratory tract. Causes burns. |
| Primary Routes of Exposure: | Contact with skin and eyes. Inhalation of vapor. |
| Eye Contact: | Causes burns to the eyes. May cause blindness. |
| Skin Contact: | Prolonged contact with skin can cause delayed, deep, and slow-healing painful burns. |
| Inhalation: | Causes chemical burns to the respiratory tract. May mimic carbon monoxide poisoning. |
| Ingestion: | Severe burns to the gastrointestinal tract may occur. |
| Acute Health Effects: | Difficulty in breathing, lung congestion, nausea, dizziness, breathlessness, burns to eyes and skin. Phosphorous trifluoride, a decomposition product, mimics carbon monoxide poisoning. |
| Chronic Health Effects: | Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate or water soluble calcium salts as antidote. Seek medical assistance. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | carbon dioxide, foam or dry powder |
| Special Fire Fighting Procedures: | If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit corrosive fumes of hydrofluoric acid and toxic phosphorous trifluoride gas. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills should be covered with calcium carbonate or limestone, and swept up. Take precautions against toxic vapors. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container away from air and moisture. Keep away from heat and direct sunlight. To maximize shelf life, store material at <10°C. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses and face shield when handling this material in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | The material must be handled in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. Only emergency situations warrant respirator use. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless to light yellow liq. |
| Molecular Weight: | 547.01 |
| Melting Point: | no data |
| Boiling Point: | ~80°C |
| Vapor Pressure: | 240mm(55°C) |
| Specific Gravity: | 2.2 |
| Odor: | odorless |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air sensitive, moisture sensitive, (store cold) |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Exposure to air, moisture, heat, and light. |
| Incompatibility: | active metals, oxidizing agents and halogens |
| Decomposition Products: | Platinum metal and phosphorous trifluoride gas. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data |
| Mutagenic Effects: | No data |
| Tetratogenic Effects: | No data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Corrosive liquids, N.O.S. |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1760 |
| Shipping Name (IATA): | Corrosive liquid, N.O.S. |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1760 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 12/19/2000 |
| Revision Date: | 12/16/2011 |