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CAS Number: 7726-95-6
Product Catalog

93-3501
Bromine Bromine (99.5%)
CAS Number: 7726-95-6
MDL Number: MFCD00010896
Molecular Formula: Br
Molecular Weight: 159.82
Chemical Formula: Br2
Color and Form: dark red liq.
Note:  

Safety: Hazardous

Physical Characteristics: melting point -7.25°C, boiling point 58.8°C, density 3.12

Transportation: Boat, truck. See MSDS sheet.

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SECTION 1: Product Identification
Chemical Name: Bromine (99.5%)
Product Number: 93-3501
CAS Registry Number: 7726-95-6
Formula: Br2
EINECS Number: 231-778-1
Chemical Family: metal or element
Synonym: Dibromine
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 7726-95-6 100 0.1ppm 0.7mg/m3
SECTION 3: Hazards Identification
Emergency Overview: Danger: Poison. Both liquid and vapor are corrosive to all body tissues and may cause serious burns, headache, cough, nosebleed, vertigo, pulmonary edema, and abdominal pain.
Primary Routes of Exposure: Inhalation, eyes, skin, ingestion
Eye Contact: Corrosive. Can cause blurred vision, redness, pain, severe tissue burns and eye damage.
Skin Contact: Corrosive! Symptoms may include skin discoloration, pain, serious burns, blistering, and slow healing ulcers.
Inhalation: Inhalation may cause serious burns, headache, cough, nosebleed, vertigo, pulmonary edema, and abdominal pain.
Ingestion: Corrosive! Sore throat, vomiting and abdominal spasms may occur. Lethal dose is quite low.
Acute Health Effects: Very toxic. Bromine is corrosive to all body tissue, resulting in pain, burns, pulmonary edema, and abdominal pain
Chronic Health Effects: Pulmonary edema, pneumonia, diarrhea, and rashes may be delayed complications of severe exposures.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
Special Fire Fighting Procedures: If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit toxic bromine and hydrobromic acid fumes.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Ventilate and evacuate area. Qualified clean-up personnel require protective clothing and respiratory protection from vapors. Small spills may be flushed with sodium bisulfite or sodium thiosulfate solution.
SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed bottle in a cool place. Handle material in an efficient fume hood.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: This product should only be handled in an efficient fume hood.
Respirator: In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: Protective apron suggested
SECTION 9: Physical and Chemical Properties
Color and Form: dark red liq.
Molecular Weight: 159.82
Melting Point: -7.25°C
Boiling Point: 58.8°C
Vapor Pressure: no data
Specific Gravity: 3.12
Odor: none
Solubility in Water: slightly soluble
SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Corrodes most metals
Incompatibility: finely divided metals, titanium powder, iodides, reducing agents, hydrazine, alkenes, acetylene, carbonyls, alcohols.
Decomposition Products: none
SECTION 11: Toxicological Information
RTECS Data: Oral (Human); LDLo: 14 mg/kg. Inhalation (Human); LCLo: 1000 ppm. Oral (rat); LD50: 2600 mg/kg. Inhalation (rat); LC50: 2700 mg/m3. Oral (mouse); LD50: 3100 mg/kg. Inhalation (mouse); LD50: 750 ppm/9M. Oral (rabbit); LD50: 4160 mg/kg. Inhalation (rabbit); LCLo: 180 ppm/6.5H. Oral (guinea pig); LD50: 5500 mg/kg. Oral (mammal-species unspecified); LD50: 440 mg/kg. Inhalation (rat); TCLo: 1400 ug/m3/17W-I.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: Avoid release into the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in the environment.
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Bromine
Hazard Class (CFR): 8 (inhalation hazard)
Additional Hazard Class (CFR): 6.1
Packaging Group (CFR): I
UN ID Number (CFR): UN# 1744
Shipping Name (IATA): PROHIBITED
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Reportable under SARA 313.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 3/20/2001
Revision Date: 7/28/2011

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