| CAS Number: | 10101-97-0 |
| MDL Number: | MFCD00149813 |
| Molecular Formula: | NiO4S |
| Molecular Weight: | 154.78 (262.86) |
| Chemical Formula: | NiSO4·6H2O |
| Color and Form: | green xtl. |
| Note: |
Physical Characteristics: density 2.07
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Nickel (II) sulfate hexahydrate (99.99%-Ni) PURATREM |
| Product Number: | 93-2856 |
| CAS Registry Number: | 10101-97-0 |
| Formula: | NiSO4.6H2O |
| EINECS Number: | 232-104-9 |
| Chemical Family: | metal sulfate |
| Synonym: | Nickelous sulfate hexahydrate, sulfuric acid, nickel(2+)salt |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 10101-97-0 | 100 | 0.1mg/m3 | 1mg/m3 |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Harmful if swallowed. Ingestion may cause intestinal disorders, convulsions, and asphyxia. May cause sensitization by inhalation and skin contact. May cause cancer and heritable genetic damage. |
| Primary Routes of Exposure: | Ingestion |
| Eye Contact: | May cause slight to mild irritation of the eyes. |
| Skin Contact: | May cause slight to mild irritation of the skin. May cause sensitization by skin contact. Prolonged contact may lead to dermatitis. |
| Inhalation: | May be irritating to the nose, mucous membranes and respiratory tract. |
| Ingestion: | Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. |
| Acute Health Effects: | Harmful if swallowed. May be irritating to skin, eyes and respiratory tract, causing intestinal disorders, convulsions, asphyxia, sensitization dermatitis, allergic asthma, and pneumonitis |
| Chronic Health Effects: | Long term exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause cancer and heritable genetic damage. |
| NTP: | Yes |
| IARC: | Yes |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | none required |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic fumes of sulfur oxides. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store material in a tightly sealed bottle away from moisture. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear appropriate chemical resistant gloves and protective clothing. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | green xtl. |
| Molecular Weight: | 154.78 (262.86) |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | not applicable |
| Specific Gravity: | 2.07 |
| Odor: | none |
| Solubility in Water: | 62.52g/100cc (0°C) |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture stable |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | active metals |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Oral (rat); LD50: 264 mg/kg. Intravenous (dog); LDLo: 89500 ug/kg. Subcutaneous (cat); LDLo: 500 mg/kg. Intravenous (cat); LDLo: 71600 ug/kg. Subcutaneous (rabbit); LDLo: 500 mg/kg. Intravenous (rabbit); LDLo: 35800 ug/kg. Subcutaneous (guinea pig); LDLo: 62 mg/kg. Oral (rat); TDLo: 163 gm/kg/2Y-C. Oral (rat); TDLo:11375 mg/kg/13W-C. Inhalation (mouse); TCLo: 3582 ug/m3/6H/12D-I. Oral (dog); TDLo: 204 gm/kg/2Y-I. Human cells-not otherwise specified; DNA damage: 5 mmol/L. Human Lymphocyte; Cytogentic analysis: 5 mg/L. Human Lymphocyte; Sister chromatid exchange: 2500 ug/L. |
| Carcinogenic Effects: | tumorigen |
| Mutagenic Effects: | mutagen |
| Tetratogenic Effects: | Insufficient data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Not listed in TSCA inventory |
| SARA (Title 313): | Title compound: See category code N495 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 10/08/2001 |
| Revision Date: | 12/08/2010 |