| CAS Number: | 4454-16-4 |
| MDL Number: | MFCD00014002 |
| Molecular Formula: | C16H30NiO4 |
| Molecular Weight: | 345.13 |
| Chemical Formula: | Ni[OOCCH(C2H5)C4H9]2 |
| Color and Form: | viscous liq. |
| Note: |
Physical Characteristics: flash point 155°F, density 1.08
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Nickel (II) 2-ethylhexanoate,78% in 2-ethylhexanoic acid (10-15% Ni) |
| Product Number: | 93-2830 |
| CAS Registry Number: | 4454-16-4 |
| Formula: | Ni[OOCCH(C2H5)C4H9]2 |
| EINECS Number: | 244-699-9 |
| Chemical Family: | metal carboxylate |
| Synonym: | 2-Ethylcaproic acid, nickel in 2-Ethylcaproic acid |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 4454-16-4 | 78 | 0.2mg/m3 (as Ni) | 1mg/m3 (as Ni) |
| 2-ethylhexanoic acid | 149-57-5 | 21 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | 2-ethyl hexanoic acid is severely irritating to eyes, skin and respiratory tract, and causes drowsiness. May cause sensitization by skin contact and may cause cancer. |
| Primary Routes of Exposure: | Ingestion, eyes, inhalation, skin |
| Eye Contact: | Causes severe irritation of the eyes. |
| Skin Contact: | Causes moderate to severe irritation of the skin. May cause sensitization by skin contact. |
| Inhalation: | Vapor will severely irritate the nose, mucous membranes and respiratory tract, and cause drowsiness. |
| Ingestion: | Ingestion may cause gastrointestinal distress, dizziness, weakness, and drowsiness. |
| Acute Health Effects: | Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact. |
| Chronic Health Effects: | Prolonged exposure to 2-ethylhexanoic acid may damage the liver. Long term exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause cancer. |
| NTP: | Yes |
| IARC: | Yes |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 155 °F |
| Autoignition Temperature: | no data |
| Explosion Limits: | none |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic fumes. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a sealed container. Keep away from heat and moisture. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear appropriate chemical resistant gloves and protective clothing. |
| Ventilation: | Material may form a vapor. If possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | viscous liq. |
| Molecular Weight: | 345.13 |
| Melting Point: | no data |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.08 |
| Odor: | organic odor |
| Solubility in Water: | insoluble |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | air and moisture stable liquid |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | oxidizing agents, bases |
| Decomposition Products: | Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. 2-Ethylhexanoic acid: Eye (rabbit) Draize: 20mg Severe; Oral (rat) LD50:3g/kg; Inhalation (rat) LC: >400 ppm/6H; Skin (rabbit) LD50: 1260 microliter/kg; Oral (rat) TDLo: 8800 mg/kg/2W-1 somnolence; Oral (rat) Reproductive: 1803 mg.Kg developmental abnormalities. |
| Carcinogenic Effects: | Carcinogen (as Ni) |
| Mutagenic Effects: | none |
| Tetratogenic Effects: | 2-Ethylhexanoic acid: reproductive effector. |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound: See Category Code N495 for reporting. |
| Second Ingredient: | 2-ethylhexanoic acid (149-57-5) listed TSCA |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 12/28/2000 |
| Revision Date: | 8/16/2011 |