| CAS Number: | 7782-64-1 |
| MDL Number: | MFCD00016222 |
| Molecular Formula: | F2Mn |
| Molecular Weight: | 92.93 |
| Chemical Formula: | MnF2 |
| Color and Form: | light brown pwdr. |
| Note: |
Stability: hygroscopic
Physical Characteristics: melting point 856°C, density 3.98
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Manganese (II) fluoride, 99% |
| Product Number: | 93-2509 |
| CAS Registry Number: | 7782-64-1 |
| Formula: | MnF2 |
| EINECS Number: | 231-960-0 |
| Chemical Family: | metal halide |
| Synonym: | Manganese difluoride, Manganous fluoride |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 7782-64-1 | 100 | 0.2mg/m3 (as Mn) | 5mg/m3 (as Mn) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Harmful by inhalation and if swallowed. Irritating to eyes, skin and respiratory tract. |
| Primary Routes of Exposure: | Contact with skin and eyes. Inhalation of dust. |
| Eye Contact: | Causes irritation to the eyes. May cause serious damage. Effects may not immediately appear. |
| Skin Contact: | Causes irritation, with redness and pain. Soluble fluoride may be corrosive. Effects may not appear immediately |
| Inhalation: | Harmful by inhalation. Inhalation of dust will cause severe irritation to the respiratory tract. |
| Ingestion: | Harmful if swallowed. May cause salivation, nausea, vomiting, diarrhea, and abdominal pain. |
| Acute Health Effects: | Irritating to eyes, skin and respiratory tract. Harmful by inhalation and if swallowed. Fluoride poisoning may cause vomiting, diarrhea, weakness, coma, respiratory failure and cardiovascular collapse. |
| Chronic Health Effects: | Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have shown manganese may decrease fertility in men. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly or water soluble calcium salts as antidote. Seek medical assistance. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | not applicable |
| Autoignition Temperature: | none |
| Explosion Limits: | none |
| Extinguishing Medium: | None. Material is non-flammable. |
| Special Fire Fighting Procedures: | No special fire fighting procedures required. |
| Hazardous Combustion and Decomposion Products: | none |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store solid in a tightly sealed container away from moisture. Handle under a dry atmosphere of air or nitrogen. Prolonged exposure to the atmosphere may degrade the product. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Material may form a fine dust. If possible, handle the material in an efficient fume hood. |
| Respirator: | If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | light brown pwdr. |
| Molecular Weight: | 92.93 |
| Melting Point: | 856°C |
| Boiling Point: | no data |
| Vapor Pressure: | no data |
| Specific Gravity: | 3.98 |
| Odor: | none |
| Solubility in Water: | .66g/100cc (40 °C) |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | hygroscopic |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with moisture |
| Incompatibility: | Mineral acids and active metals |
| Decomposition Products: | none |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Subcutaneous (frog); LDLo: 224 mg/kg. |
| Carcinogenic Effects: | no data |
| Mutagenic Effects: | no data |
| Tetratogenic Effects: | no data |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Non-hazardous |
| Hazard Class (CFR): | NA |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | NA |
| UN ID Number (CFR): | NA |
| Shipping Name (IATA): | Non-hazardous |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | NA |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound: See Category Code N450 for reporting. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 6/11/2001 |
| Revision Date: | 12/14/2011 |