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CAS Number: 3115-68-2
Product Catalog

93-1579
Phosphorus Tetra-n-butylphosphonium bromide, 98%
CAS Number: 3115-68-2
MDL Number: MFCD00011853
Molecular Formula: C16H36BrP
Molecular Weight: 339.35
Chemical Formula: (C4H9)4P+Br-
Color and Form: white xtl.
Note:  

Stability: hygroscopic

Safety: Hazardous

Physical Characteristics: melting point 100-103°C

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SECTION 1: Product Identification
Chemical Name: Tetra-n-butylphosphonium bromide, 98%
Product Number: 93-1579
CAS Registry Number: 3115-68-2
Formula: (C4H9)4P+Br-
EINECS Number: 221-487-8
Chemical Family: organophosphorus compound
Synonym: Tetra-N-butylphosphonium bromide
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 3115-68-2 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Causes severe irritation to skin, eyes and respiratory tract. Harmful if swallowed. Very toxic in contact with skin. From animal studies may cause nervous system effects at high dose.
Primary Routes of Exposure: Eye, skin, ingestion
Eye Contact: Causes severe irritation of the eyes.
Skin Contact: Causes severe irritation of the skin. Very toxic in contact with skin.
Inhalation: Dust is irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Harmful if swallowed. Irritating to mouth, throat and stomach. May cause nausea, diarrhea and vomiting.
Acute Health Effects: Irritating to skin, eyes and respiratory tract. Harmful if swallowed. Very toxic in contact with skin.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: dry chemical, carbon dioxide, water, or foam.
Special Fire Fighting Procedures: Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: In a fire material may emit toxic organic fumes, carbon monoxide, hydrogen bromide, and phosphorous oxides.
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a cool, dry, area away from heat. Handle in a dry atmosphere.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 339.35
Melting Point: 100-103°C
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: very soluble
SECTION 10: Stability and Reactivity
Stability: hygroscopic
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with moisture
Incompatibility: oxidizing agents and chlorine
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes, hydrogen bromide, and phosphorus pentoxide.
SECTION 11: Toxicological Information
RTECS Data: Administration onto the skin (rabbit); Standard Draize test: 500 mg. Administration into the eye (rabbit); Standard Draize test: 100 uL/24H. Oral (rat); LD50: 420 mg/kg. Inhalation (rat); LD50: >3 mg/m3/1H. Intravenous (mouse); LD50: 56 mg/kg. Administration onto the skin (rabbit); LD50: 197 mg/kg.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Toxic solids, organic, N.O.S.
Hazard Class (CFR): 6.1
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 2811
Shipping Name (IATA): Toxic solid, Organic, N.O.S.
Hazard Class (IATA): 6.1
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 2811
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 5/14/2001
Revision Date: 7/28/2011

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