| CAS Number: | 76-86-8 |
| MDL Number: | MFCD00000496 |
| Molecular Formula: | C18H15ClSi |
| Molecular Weight: | 294.9 |
| Chemical Formula: | (C6H5)3SiCl |
| Color and Form: | white xtl. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: melting point 91-92°C, boiling point 378°C
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Triphenylchlorosilane, 97% |
| Product Number: | 93-1466 |
| CAS Registry Number: | 76-86-8 |
| Formula: | (C6H5)3SiCl |
| EINECS Number: | 200-989-0 |
| Chemical Family: | organosilicon compounds |
| Synonym: | Triphenylsilicon chloride, Triphenyl chloride |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 76-86-8 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Corrosive hydrogen chloride gas and liquids released upon contact with moisture. Corrosive to skin, eyes and mucous membranes. May be harmful if swallowed. Inhalation of vapor or mists may be fatal. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin, eyes. |
| Eye Contact: | Corrosive to eyes. Causes eye burns and corneal damage |
| Skin Contact: | Contact with moisture of skin produces corrosive hydrogen chloride. |
| Inhalation: | Inhalation causes inflammation of the respiratory tract, edema and chemical pneumonitis. Inhalation may be fatal. |
| Ingestion: | Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset. |
| Acute Health Effects: | Contact with skin, eyes and mucous membranes causes burns. Ingestion causes burns to the gastrointestinal tract. Inhalation may be fatal due to inflammation, edema and chemical pneumonitis. |
| Chronic Health Effects: | No information available on long-term chronic effects. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | no data |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide or dry powder |
| Special Fire Fighting Procedures: | Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | 'If involved in a fire this material may emit toxic organic fumes and silica dust particulate. |
| Unusual Fire or Explosion Hazards: | No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Spillage in areas not adequately ventilated will require an evacuation of area. Emergency response teams will require self-contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Handle and store the material under a dry atmosphere of nitrogen or argon. Keep in a cool well ventilated place away from sources of ignition. Periodically check bottle caps for cracks. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional protection. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | A rubber apron is recommended. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | white xtl. |
| Molecular Weight: | 294.9 |
| Melting Point: | 91-92°C |
| Boiling Point: | 378°C |
| Vapor Pressure: | no data |
| Specific Gravity: | no data |
| Odor: | biting odor |
| Solubility in Water: | reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Contact with moisture |
| Incompatibility: | Water, strong bases, strong oxidizing agents and halogens |
| Decomposition Products: | carbon dioxide, carbon monoxide, silicon dioxide, hydrogen chloride and organic fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | Intravenous (mouse); LD50: 56 mg/kg. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to federal, state, and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Corrosive solids, N.O.S. |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1759 |
| Shipping Name (IATA): | Corrosive solid, N.O.S. |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1759 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 11/14/2002 |
| Revision Date: | 7/29/2011 |