| CAS Number: | 75-24-1 |
| MDL Number: | MFCD00008252 |
| Molecular Formula: | C3H9Al |
| Molecular Weight: | 72.09 |
| Chemical Formula: | (CH3)3Al |
| Color and Form: | colorless liq. |
| Note: |
Price Note: price inc. non-ret. cyl.
Stability: moisture sensitive
Safety: Hazardous, pyrophoric
Physical Characteristics: melting point 15.4°C, boiling point 20°C/8 mm, flash point -1°F, density 0.752 (20°C)
Transportation: Boat, truck. See MSDS sheet.
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Trimethylaluminum, min. 98%(Material sold in non-returnable cylinder) |
| Product Number: | 93-1360 |
| CAS Registry Number: | 75-24-1 |
| Formula: | (CH3)3Al |
| EINECS Number: | 200-853-0 |
| Chemical Family: | metal alkyl |
| Synonym: | Trimethylalane |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 75-24-1 | 100 | 2mg/m3 (as Al- | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Extremely flammable liquid. Will ignite spontaneously on contact with air. Contact with skin may result in severe chemical burns. |
| Primary Routes of Exposure: | Eyes, skin and inhalation |
| Eye Contact: | Material is a severe corrosive of the eyes. |
| Skin Contact: | Contact with the skin will result in severe chemical burns as the material may spontaneously ignite. |
| Inhalation: | Combustion products may be irritating to respiratory tract. |
| Ingestion: | Ingestion is an unlikely mode of entry as the material is pyrophoric and has a noxious odor. |
| Acute Health Effects: | Corrosive to skin, eyes, and respiratory tract. |
| Chronic Health Effects: | No information available on long term exposure to this material. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 15 minutes. A victim will need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove victim to fresh air immediately. Keep the victim lying down and warm. Give oxygen as soon as possible. If shock occurs, respond with appropriate first aid. Transport the victim to a hospital. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give water to dilute the toxin (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | pyrophoric |
| Autoignition Temperature: | pyrophoric |
| Explosion Limits: | no data available |
| Extinguishing Medium: | dry chemical or foam |
| Special Fire Fighting Procedures: | Material will spontaneously ignite when exposed to air. Fire fighters must be equipped with a NIOSH-approved positive pressure self-contained breathing apparatus. |
| Hazardous Combustion and Decomposion Products: | carbon monoxide, carbon dioxide, aluminum oxide, and organic fumes. |
| Unusual Fire or Explosion Hazards: | Pyrophoric material. Will spontaneously ignite if exposed to air. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | If spilled, the product will ignite. All personnel must be immediately evacuated and the area sealed off. The material may ignite releasing toxic and corrosive fumes. Ventilation should be available. If entry into the area is required, personnel should be fitted with a self-contained breathing apparatus. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Material must be stored in a steel container under and inert atmosphere of nitrogen or argon. Store at room temperature. Keep away from heat. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses. When handling this substance wear a face shield as added protection. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | It is imperative that this product is handled in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liq. |
| Molecular Weight: | 72.09 |
| Melting Point: | 15.4°C |
| Boiling Point: | 20°C/8 mm |
| Vapor Pressure: | 9mm (20°C) |
| Specific Gravity: | 0.752 (20°) |
| Odor: | none |
| Solubility in Water: | reacts violently with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | Pyrophoric. Reacts violently with water |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | contact with air, water and alcohols |
| Incompatibility: | Water, alcohols, carbonyl compounds, mineral acids, metal salts, metals and chlorinated hydrocarbons |
| Decomposition Products: | carbon dioxide, carbon monoxide, organic fumes, and aluminum oxide. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No specific information available on this product. |
| Carcinogenic Effects: | No information available. |
| Mutagenic Effects: | No information available. |
| Tetratogenic Effects: | No information available. |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available. |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of this material according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Organometallic substance,Liquid,Pyrophoric,Water-reactive |
| Hazard Class (CFR): | 4.2 |
| Additional Hazard Class (CFR): | 4.3 |
| Packaging Group (CFR): | I |
| UN ID Number (CFR): | UN# 3394 |
| Shipping Name (IATA): | Forbidden |
| Hazard Class (IATA): | NA |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | NA |
| UN ID Number (IATA): | UN# 3394 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory |
| SARA (Title 313): | Not reportable under SARA Title 313. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 8/17/2000 |
| Revision Date: | 3/09/2011 |