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CAS Number: 1302-81-4
Product Catalog

93-1353
Aluminum Aluminum sulfide (99+%-Al) (1/4'' and down pieces)
CAS Number: 1302-81-4
MDL Number: MFCD00014162
Molecular Formula: Al2S3
Molecular Weight: 150.16
Chemical Formula: Al2S3
Color and Form: gray pieces
Note:  

Stability: moisture sensitive

Safety: Hazardous

Physical Characteristics: melting point 1100°C, density 2.02

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SECTION 1: Product Identification
Chemical Name: Aluminum sulfide (99+%-Al) (1/4 and down pieces)
Product Number: 93-1353
CAS Registry Number: 1302-81-4
Formula: Al2S3
EINECS Number: 215-109-0
Chemical Family: metal chalcogenides
Synonym: none
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 1302-81-4 100 no data no data
SECTION 3: Hazards Identification
Emergency Overview: Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure: Ingestion, inhalation, skin and eyes
Eye Contact: Dust causes mild to moderate irritation of the eyes.
Skin Contact: Causes slight irritation of the skin.
Inhalation: Inhalation of dust will lead to irritation of the respiratory tract. Hydrogen sulfide gas, if formed, is poisonous.
Ingestion: No information on the physiological effects of ingestion.
Acute Health Effects: Hydrogen sulfide, if released, causes nausea, dizziness and pulmonary edema.
Chronic Health Effects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide or dry powder
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit irritating fumes of hydrogen sulfide and sulfur dioxide.
Unusual Fire or Explosion Hazards: Flammable solid. Formation of explosive air/dust mixtures is possible.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Remove sources of ignition. Do not raise dust. Mix with vermiculite, sodium carbonate or other suitable dry non combustible adsorbent and sweep up.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Exposure to the atmosphere may lead to release of toxic hydrogen sulfide gas. Empty containers may retain product residues that evolve toxic gases.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: If possible, handle the material in an efficient fume hood.
Respirator: If ventilation is not available a respirator should be worn. The use of a respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: gray pieces
Molecular Weight: 150.16
Melting Point: 1100°C
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: 2.02
Odor: odor of sulfur
Solubility in Water: reacts with water
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with air, water, and mineral acids. Reaction with mineral acids can lead to formation of toxic fumes of hydrogen sulfide.
Incompatibility: Oxidizing agents, active metals, water and mineral acids
Decomposition Products: hydrogen sulfide, sulfur dioxide, and metal oxides.
SECTION 11: Toxicological Information
RTECS Data: No specific information available on this product.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: No information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.
SECTION 14: Transportation
Shipping Name (CFR): Water reactive solid, Flammable N.O.S.
Hazard Class (CFR): 4.3
Additional Hazard Class (CFR): 4.1
Packaging Group (CFR): I
UN ID Number (CFR): UN# 3132
Shipping Name (IATA): Water reactive solid, Flammable, N.O.S.
Hazard Class (IATA): 4.3
Additional Hazard Class (IATA): 4.1
Packaging Group (IATA): I
UN ID Number (IATA): UN# 3132
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 10/29/2001
Revision Date: 8/05/2011

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