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CAS Number: 2269-22-9
Product Catalog
93-1308
Aluminum › Aluminum s-butoxide, 98%| CAS Number: | 2269-22-9 |
| MDL Number: | MFCD00009327 |
| Molecular Formula: | C12H27AlO3 |
| Molecular Weight: | 246.33 |
| Chemical Formula: | Al(OC4H9)3 |
| Color and Form: | colorless liq. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: boiling point 200-206°C/30 mm, flash point 82°F, density 0.9671
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Aluminum s-butoxide, 98% |
| Product Number: | 93-1308 |
| CAS Registry Number: | 2269-22-9 |
| Formula: | Al(OC4H9)3 |
| EINECS Number: | 218-871-2 |
| Chemical Family: | metal alkoxide |
| Synonym: | Aluminum 2-butanolate |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 2269-22-9 | 100 | no data | no data |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Corrosive to skin, eyes, and respiratory system. Moisture will produce aluminum oxide powder and s-butanol vapor which may cause severe eye irritation and drowsiness. Possible risk of harm to the unborn child. |
| Primary Routes of Exposure: | Inhalation, ingestion, contact with skin and eyes. |
| Eye Contact: | Causes burns to the eyes. |
| Skin Contact: | Causes burns to the skin. |
| Inhalation: | Corrosive to the nose, mucous membranes and respiratory tract. |
| Ingestion: | Ingestion may cause gastrointestinal distress, nausea, vomiting, headache and damage to the mouth, throat and esophagus. |
| Acute Health Effects: | Corrosive to skin, eyes and respiratory tract. Causes burns. May cause damage to the mouth, throat and esophagus. Possible risk of harm to the unborn child. |
| Chronic Health Effects: | No data is available for this product. In animal studies, s-butanol in high doses has acted as a reproductive effector. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 82 °F |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | carbon dioxide, dry powder or foam |
| Special Fire Fighting Procedures: | If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may emit toxic organic fumes. |
| Unusual Fire or Explosion Hazards: | Flammable liquid. Formation of explosive air/vapor mixtures is possible in presence of moisture. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Eliminate all ignition sources. Avoid contact with water. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable adsorbent, and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Store in a tightly sealed container in a dry place. With air may slowly form explosive peroxides. If container is left open, product may adsorb moisture and release s-butanol vapor. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | Material may form a vapor upon exposure to air. if possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless liq. |
| Molecular Weight: | 246.33 |
| Melting Point: | no data |
| Boiling Point: | 200-206°C/30 mm |
| Vapor Pressure: | no data |
| Specific Gravity: | 0.9671 |
| Odor: | glue like odor |
| Solubility in Water: | Reacts with water |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive liquid |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | Keep away from moisture, heat and ignition sources including open flame and electrostatic discharge. |
| Incompatibility: | Oxidizing agents, water, active metals and halogens |
| Decomposition Products: | Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No specific information available on this product. Sec-butanol: oral (rat) LD50: 2193 mg/kg; inh (rat) lclo: 16000 ppm/4h; skin (rat) LD50: >2 gm/kg; intraperitoneal (rat) LD50: 1193 mg/kg; oral (dog) LDLo: 2400 mg/kg; oral (rbt) LD50: 4893 mg/kg; inh (rat) TCLo: 500 ppm/6h/5d-i; inhalation (rat) TCLo-repro: 5000 ppm/7h |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | s-butanol: Reproductive effector |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to local, state and federal regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Flammable liquids, Corrosive, N.O.S. |
| Hazard Class (CFR): | 3 |
| Additional Hazard Class (CFR): | 8 |
| Packaging Group (CFR): | III |
| UN ID Number (CFR): | UN# 2924 |
| Shipping Name (IATA): | Flammable liquid, Corrosive, N.O.S. |
| Hazard Class (IATA): | 3 |
| Additional Hazard Class (IATA): | 8 |
| Packaging Group (IATA): | III |
| UN ID Number (IATA): | UN# 2924 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 2/26/2001 |
| Revision Date: | 12/23/2011 |
