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CAS Number: 19200-21-6
Product Catalog

93-0739
Phosphorus Nitronium hexafluorophosphate, min. 97%
CAS Number: 19200-21-6
MDL Number: MFCD00031520
Molecular Formula: F6NO2P
Molecular Weight: 190.97
Chemical Formula: NO2PF6
Color and Form: white xtl.
Note:  

Stability: moisture sensitive

Safety: Hazardous

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SECTION 1: Product Identification
Chemical Name: Nitronium hexafluorophosphate, min. 97%
Product Number: 93-0739
CAS Registry Number: 19200-21-6
Formula: NO2PF6
EINECS Number: 242-872-7
Chemical Family: metal fluorophosphate complex
Synonym: Nitryl hexafluorophosphate
SECTION 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 19200-21-6 100 2.5mg/m3 (as F) 2.5mg/m3 (as F)
SECTION 3: Hazards Identification
Emergency Overview: This compound may slowly hydrolyze in the presence of water to give toxic nitrogen dioxide and corrosive fluorophosphoric acid. The latter can cause fluoride poisoning, symptoms: nausea, vomiting, and weakness
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes.
Eye Contact: Dust is corrosive to the eyes. Exposure can lead to permanent eye damage.
Skin Contact: Corrosive to skin. Contact can lead to redness, pain, blistering, ulceration, and scar formation.
Inhalation: Causes burns to the nose, mucous membranes and respiratory tract. Pulmonary edema may occur.
Ingestion: May cause salivation, nausea, vomiting, diarrhea, and abdominal pain.
Acute Health Effects: Burns to eyes, skin, and respiratory tract. Dust: Fluoride poisoning may cause nausea, vomiting, diarrhea, weakness, coma, respiratory failure and cardiovascular collapse.
Chronic Health Effects: Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.
NTP: No
IARC: No
OSHA: No
SECTION 4: First Aid Measures
Eye Exposure: Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure: Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical assistance if irritation persists.
Inhalation: Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.
SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: not applicable
Explosion Limits: not applicable
Extinguishing Medium: dry chemical, carbon dioxide, water fog, or foam.
Special Fire Fighting Procedures: If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products: If involved in a fire this material may emit corrosive fluorophosphoric acid.
Unusual Fire or Explosion Hazards: May act as an oxygen source in a fire. May liberate pressurizing gas if strongly heated.
SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be absorbed into vermiculite, diatomaceous earth, or other suitable chemical absorbent. Sweep up the material and dispose of properly.
SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container. Keep away from heat, moisture and direct sunlight. If moisture is present, glass storage bottle may become etched.
SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and clothing.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Respirator: In the absence of adequate ventilation a respirator should be worn. The use of a respirator requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection: No additional protection required.
SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 190.97
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: none
Solubility in Water: soluble
SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: mineral acids, oxidizing agents and active metals
Decomposition Products: nitrogen oxides and phosphorus trifluoride
SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data
SECTION 12: Ecological Information
Ecological Information: no information available
SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.
SECTION 14: Transportation
Shipping Name (CFR): Corrosive solids, N.O.S.
Hazard Class (CFR): 8
Additional Hazard Class (CFR): NA
Packaging Group (CFR): II
UN ID Number (CFR): UN# 1759
Shipping Name (IATA): Corrosive solid, N.O.S.
Hazard Class (IATA): 8
Additional Hazard Class (IATA): NA
Packaging Group (IATA): II
UN ID Number (IATA): UN# 1759
SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none
Third Ingredient: none
SECTION 16: Other Information
Disclaimer: The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date: 5/23/2004
Revision Date: 12/20/2011

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