CAS Number: 57-14-7
Product Catalog

93-0720

Nitrogen › 1,1-Dimethylhydrazine, 98%

CAS Number:	57-14-7
MDL Number:	MFCD00007628
Molecular Formula:	C2H8N2
Molecular Weight:	60.10
Chemical Formula:	(CH3)2NNH2
Color and Form:	colorless to pale yellow liq.
Note:	For sale in USA. For other countries contact Strem.

Stability: store cold

Safety: Hazardous

Physical Characteristics: boiling point 62-64°C/753 mm, flash point 34°F, density 0.791

Transportation: Boat, truck, for sale in usa only. See MSDS sheet.

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SECTION 1: Product Identification
Chemical Name:	1,1-Dimethylhydrazine, 98%
Product Number:	93-0720
CAS Registry Number:	57-14-7
Formula:	(CH3)2NNH2
EINECS Number:	200-316-0
Chemical Family:	organic compound
Synonym:	Dimethylhydrazine, uns-Dimethylhydrazine

SECTION 2: Composition and Information on Ingredients
Ingredient	CAS Number	Percent	ACGIH (TWA)	OSHA (PEL)
Title Compound	57-14-7	100	0.15 mg/m3	1mg/m3 (skin)

SECTION 3: Hazards Identification
Emergency Overview:	Toxic by inhalation and if swallowed. Causes burns to eyes, skin and respiratory tract. May causes cancer and heritable genetic damage.
Primary Routes of Exposure:	Ingestion, inhalation of dust and vapor
Eye Contact:	Causes burns to the eyes.
Skin Contact:	Causes caustic burns to the skin.
Inhalation:	Causes respiratory tract burns. Symptoms may include coughing, shortness of breath, dizziness, nausea and vomiting.
Ingestion:	Toxic. Ingestion may lead to burning sensation, dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Acute Health Effects:	Toxic by inhalation and if swallowed. Causes burns to skin, eyes and respiratory tract. Liquid is toxic and corrosive if swallowed, inhaled or absorbed through skin. Induces sleepiness.
Chronic Health Effects:	Potential occupational carcinogen [in animals: tumors of the lungs, liver, blood vessels & intestines] May cause cancer and heritable genetic damage.
NTP:	No
IARC:	yes
OSHA:	No

SECTION 4: First Aid Measures
Eye Exposure:	Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention.
Skin Exposure:	Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists.
Inhalation:	Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion:	Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:	34°F
Autoignition Temperature:	247°C
Explosion Limits:	2-95%
Extinguishing Medium:	carbon dioxide, dry powder, or foam (Not water)
Special Fire Fighting Procedures:	Water spreads toxic soluble cmpd to environment. Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and Decomposion Products:	If involved in a fire this material may emit irritating fumes, nitrogen oxides, and nitrogen under pressure.
Unusual Fire or Explosion Hazards:	Flammable liquid. May become unstable and liberate gas in closed containers over 51�C

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:	Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up. Spillage in areas not adequately ventilated may require an evacuation of area. Emergency response teams will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
Handling and Storage:	Store in tightly closed containers in a cool, well ventilated area away from air, heat and moisture

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:	Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:	Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:	The material must be handled in an efficient fume hood.
Respirator:	If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Additional Protection:	No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:	colorless to pale yellow liq.
Molecular Weight:	60.1
Melting Point:	no data
Boiling Point:	62-64°C/753 mm
Vapor Pressure:	157mm (25°C)
Specific Gravity:	0.791
Odor:	ammonia or fish-like odor
Solubility in Water:	very soluble

SECTION 10: Stability and Reactivity
Stability:	Hygroscopic. Store cold
Hazardous Polymerization:	no hazardous polymerization
Conditions to Avoid:	May ignite spontaneously in contact with oxidizers.
Incompatibility:	oxidizing agents, hydrogen peroxide, nitric acid, perchloric acid, copper/copper alloys, iron and iron salts.
Decomposition Products:	carbon monoxide, nitrogen oxides, nitrogen, organic fumes

SECTION 11: Toxicological Information
RTECS Data:	Oral (rat); LD50: 122 mg/kg. Inhalation (rat); LC50: 252 ppm/4H. Intraperitoneal (rat); LD50: 102 mg/kg. Intravenous (rat); LD50: 119 mg/kg. Intratracheal (rat) LDLo: 27 mg/kg. Oral (mouse); LD50: 265 mg/kg. Inhalation (mouse); LC50: 172 ppm/4H. Intraperitoneal (mouse); LD50: 113 mg/kg. Administration onto the skin (dog); LDLo: 301 mg/kg. Administration onto the skin (rabbit); LD50: 1060 mg/kg. Oral (rat); TD: 300 mg/kg/14W-I. Human cells-not otherwise specified; morphological transformation: 167 umol/L. Human Fibroblast; DNA damage: 300 umol/L. DNA (rat liver) 30 micromol/L
Carcinogenic Effects:	Tumorigen
Mutagenic Effects:	Mutagen
Tetratogenic Effects:	Reproductive effector

SECTION 12: Ecological Information
Ecological Information:	When administered in the drinking water, 1,1-dimethylhydrazine induced tumors of the kidneys, lungs, and liver in mice . A reportable quantity (RQ) of 10 lb is in effect under CERCLA.

SECTION 13: Disposal Considerations
Disposal:	Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):	Dimethylhydrazine, unsymmetrical
Hazard Class (CFR):	6.1 (inhalation hazard)
Additional Hazard Class (CFR):	3& 8
Packaging Group (CFR):	I
UN ID Number (CFR):	UN# 1163
Shipping Name (IATA):	Prohibited
Hazard Class (IATA):	NA
Additional Hazard Class (IATA):	NA
Packaging Group (IATA):	NA
UN ID Number (IATA):	UN# 1163

SECTION 15: Regulatory Information
TSCA:	Listed in the TSCA inventory.
SARA (Title 313):	Title compound listed, sec. 313
Second Ingredient:	none
Third Ingredient:	none

SECTION 16: Other Information
Disclaimer:	The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information.
Preparation Date:	7/10/2002
Revision Date:	12/19/2011