| CAS Number: | 373-61-5 |
| MDL Number: | MFCD00036359 |
| Molecular Formula: | BF3 |
| Molecular Weight: | 187.91 |
| Chemical Formula: | BF3·2CH3COOH |
| Color and Form: | colorless to pale yellow liq. |
| Note: |
Stability: moisture sensitive
Safety: Hazardous
Physical Characteristics: density 1.353
| SECTION 1: Product Identification | |
|---|---|
| Chemical Name: | Boron fluoride, acetic acid complex, min. 97% |
| Product Number: | 93-0517 |
| CAS Registry Number: | 373-61-5 |
| Formula: | BF3.2CH3COOH |
| EINECS Number: | 206-768-5 |
| Chemical Family: | metal halide |
| Synonym: | Boron trifluoride-acetic acid complex |
| SECTION 2: Composition and Information on Ingredients | ||||
|---|---|---|---|---|
| Ingredient | CAS Number | Percent | ACGIH (TWA) | OSHA (PEL) |
| Title Compound | 373-61-5 | 100 | 2.5mg/m3 (as F) | 2.5mg/m3 (as F) |
| SECTION 3: Hazards Identification | |
|---|---|
| Emergency Overview: | Material is extremely destructive to mucous membranes, respiratory tract, eyes and skin. Inhalation may be fatal. Boron poisoning causes depression of circulation, vomiting, diarrhea, shock, and coma. |
| Primary Routes of Exposure: | Ingestion, inhalation, skin and eyes. |
| Eye Contact: | Causes burns to the eyes. |
| Skin Contact: | Causes burns to the skin. |
| Inhalation: | Destructive to tissues of the nose, mucous membranes and respiratory tract. Inhalation may be fatal. |
| Ingestion: | Ingestion may cause tissue damage of the esophagus. High doses may cause boron poisoning. |
| Acute Health Effects: | Destructive to skin, eyes and respiratory tract. High doses may cause convulsions, cyanosis, coma and death. |
| Chronic Health Effects: | Repeated ingestion of some boron compounds may cause dryness of mucous membranes, anorexia, vomiting, mild diarrhea, skin rash, and low blood cell count. Kidney damage may occur. |
| NTP: | No |
| IARC: | No |
| OSHA: | No |
| SECTION 4: First Aid Measures | |
|---|---|
| Eye Exposure: | Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need assistance in keeping their eye lids open. Get immediate medical attention. |
| Skin Exposure: | Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if irritation persists. |
| Inhalation: | Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. |
| Ingestion: | Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce vomiting only if directed by medical personnel. |
| SECTION 5: Fire Fighting Measures | |
|---|---|
| Flash Point: | 84°C |
| Autoignition Temperature: | no data |
| Explosion Limits: | no data |
| Extinguishing Medium: | dry chemical, carbon dioxide, water, or foam. |
| Special Fire Fighting Procedures: | Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus and full protective clothing. |
| Hazardous Combustion and Decomposion Products: | If involved in a fire this material may form toxic boron oxide dust. |
| Unusual Fire or Explosion Hazards: | Flammable liquid. No unusual fire or explosion hazards. |
| SECTION 6: Accidental Release Measures | |
|---|---|
| Spill and Leak Procedures: | Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and swept up. |
| SECTION 7: Handling and Storage | |
|---|---|
| Handling and Storage: | Handle and store the material under a dry atmosphere of nitrogen or argon. Keep away from heat. |
| SECTION 8: Exposure Controls and Personal Protection | |
|---|---|
| Eye Protection: | Always wear approved safety glasses when handling a chemical substance in the laboratory. |
| Skin Protection: | Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. |
| Ventilation: | If possible, handle the material in an efficient fume hood. |
| Respirator: | If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134. |
| Additional Protection: | No additional protection required. |
| SECTION 9: Physical and Chemical Properties | |
|---|---|
| Color and Form: | colorless to pale yellow liq. |
| Molecular Weight: | 187.91 |
| Melting Point: | -47°C |
| Boiling Point: | 140-148°C |
| Vapor Pressure: | no data |
| Specific Gravity: | 1.353 |
| Odor: | pungent |
| Solubility in Water: | reacts with water to form hydrate |
| SECTION 10: Stability and Reactivity | |
|---|---|
| Stability: | moisture sensitive |
| Hazardous Polymerization: | no hazardous polymerization |
| Conditions to Avoid: | none |
| Incompatibility: | mineral acids, oxidizing agents, aldehydes, ketones and halogens |
| Decomposition Products: | Borane, acetic acid, boron trifluoride, carbon monoxide, carbon dioxide, and organic fumes. |
| SECTION 11: Toxicological Information | |
|---|---|
| RTECS Data: | No information available in the RTECS files. |
| Carcinogenic Effects: | No data available |
| Mutagenic Effects: | No data available |
| Tetratogenic Effects: | No data available |
| SECTION 12: Ecological Information | |
|---|---|
| Ecological Information: | No information available |
| SECTION 13: Disposal Considerations | |
|---|---|
| Disposal: | Dispose of according to federal, state, and local regulations. |
| SECTION 14: Transportation | |
|---|---|
| Shipping Name (CFR): | Boron trifluoride-acetic acid complex, Liquid |
| Hazard Class (CFR): | 8 |
| Additional Hazard Class (CFR): | NA |
| Packaging Group (CFR): | II |
| UN ID Number (CFR): | UN# 1742 |
| Shipping Name (IATA): | Boron trifluoride-acetic acid complex, Liquid |
| Hazard Class (IATA): | 8 |
| Additional Hazard Class (IATA): | NA |
| Packaging Group (IATA): | II |
| UN ID Number (IATA): | UN# 1742 |
| SECTION 15: Regulatory Information | |
|---|---|
| TSCA: | Listed in the TSCA inventory. |
| SARA (Title 313): | Title compound not listed. |
| Second Ingredient: | none |
| Third Ingredient: | none |
| SECTION 16: Other Information | |
|---|---|
| Disclaimer: | The information herein is believed to be accurate and reliable as of the date compiled. However, Strem Chemicals, Inc. makes no representation, warranty, or guarantee of any kind with respect to the information contained in this document or any use of the product based on this information. |
| Preparation Date: | 7/17/2002 |
| Revision Date: | 12/16/2011 |